Alkoxycarbonyl Groups in Metalloesters Showing Oxocarbenium‐like Structure and Alkylating Reactivity
Yingzhuang Xu,
Bingjian Feng,
Songyi Li
et al.
Abstract:In contrast to the well‐documented acylating reactivity, the alkylating reactivity of the alkoxycarbonyl group, as signified by its oxocarbenium‐like resonance structure, remains almost unexplored. Herein, the first series of Co/Ni dinuclear metalloesters exhibiting the novel oxocarbenium‐like alkoxycarbonyl groups were synthesized and characterized. In these deformed alkoxycarbonyl groups, the Ccarbonyl–Oalkoxyl bonds were contracted to 1.177(11) ~ 1.191(9) Å with the elongations of the Ccarbonyl=Ocarbonyl bo… Show more
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