Alkoxy(alkyl)silylalkyl derivatives of nitrogen-containing heterocycles

Pentacoordinate organosilicon compounds— molecular structure and stereodynamic behavior of (trifluorosilylmethyl)succinimide and (trifluorosilylmethyl)glutarimide

“…The compounds were called dragonoids because their structure is like a famous alchemists' symbol, namely, dragon devouring his tail [1]. Hypervalent organosilicon complexes with N → Si coordinate bond (structures B and C) [2][3][4][5][6][7] can also be classified as dragonoids. The synthesis, structure, and reactivity of the compounds having OCSiF 3 coordinate framework have been extensively studied [8][9][10][11][12] and reviewed [1,13,14].…”