Alkaline earth metal and lanthanide ethylene glycol carboxylates for metal oxide layer formation by spin coating

Catalysts Originating from Tailor‐made Metal Ethylene Glycol Carboxylates

“…Due to the straightforwardness of the synthesis of ethylene glycol metal carboxylates (see earlier) and their excellent lowtemperature decomposition behavior giving access to M and M x O y NPs, these complexes show great versatility in a wide range of applications. [57,63,76,86,[96][97][98][99][100][101][102][103][104] Apart from catalysis, these metal carboxylates allow, e. g. for (semi)conductive and magnetic layer deposition and pattern printing even on flexible Figure 7. A) SEM image of a sintered Ag droplet (A, top) and the profilometer image of an inkjet printed and dried droplet (A, bottom) using 2 as metal precursor.…”

“…substrates (polymers) by using CVD (Cu, Ag, Ru), [86,96,97] CCVD (Au, Ag, Mn 2 O 3 , Co 3 O 4 ), [57,63,98] [99,105,106] ink-jet printing (Cu, Ag, Au, Ru), [68,92,[101][102][103] dip-pen-lithography (Ag), [100] and joining of different materials [104] (Figure 7). The particular inks can be formulated to a high metal content using both polar and apolar solvents, ranging from water to toluene (vide supra).…”

“…Due to the straightforwardness of the synthesis of ethylene glycol metal carboxylates (see earlier) and their excellent low‐temperature decomposition behavior giving access to M and M x O y NPs, these complexes show great versatility in a wide range of applications [57,63,76,86,96–104] . Apart from catalysis, these metal carboxylates allow, e. g .…”

“…Apart from catalysis, these metal carboxylates allow, e. g . for (semi)conductive and magnetic layer deposition and pattern printing even on flexible substrates (polymers) by using CVD (Cu, Ag, Ru), [86,96,97] CCVD (Au, Ag, Mn 2 O 3 , Co 3 O 4 ), [57,63,98] spin‐coating (MgO, Y 2 O 3 , Y 0.8 Ce 0.2 O 1.6 , La 2 Ce 2 O 7 , SrBi 2 Nb 2 O 9 , (Nb x Ta 1‐x ) 2 O 9 , Ba x Sr y Ti z O), [99,105,106] ink‐jet printing (Cu, Ag, Au, Ru), [68,92,101–103] dip‐pen‐lithography (Ag), [100] and joining of different materials [104] (Figure 7). The particular inks can be formulated to a high metal content using both polar and apolar solvents, ranging from water to toluene (vide supra ).…”

Twin Polymerization: A Unique Strategy towards Versatile Functional Materials

“…When metal carboxylates such as [M(O 2 CCH 2 (OCH 2 CH 2 ) n OMe) m ] (n = 1, 2; m = 2, M = Mg, Ca, Mn, Fe, Co, Ni, Cu; m = 3, M = Y, La, Ce,) are used, then the appropriate metal oxides are formed. [70][71][72] In 2009 we demonstrated that [Ag(O 2 CCH 2 (OCH 2 CH 2 ) 2 OMe)] could be successfully used as NP source for the formation of Ag NP-loaded silica. [64] In 2015 Schliebe et al showed that Ag NP-loaded carbon and silica materials can be generated using TP in presence of [(PPh 3 )Ag(2-OCH 2 À c C 4 H 3 S)].…”