Aliovalent Substitution in Li3InCl6: A Combined Experimental and Computational Investigation of Structure and Ion Diffusion in Lithium-Halide Solid State Electrolytes
Camilla Rosa,
Marco Ravalli,
Nicolò Pianta
et al.
Abstract:Metal-halide superionic conductors are promising electrolytes for solid state Li-ion batteries. Their transport properties may be effectively influenced by doping and a synthetic approach. In this study, a combination of experimental (neutron and X-ray diffraction, total scattering techniques, solid state NMR, impedance spectroscopy) and computational techniques is used to investigate the Li 3 InCl 6 system and, in particular, the effect of Nb substitution on the In site. A maximum conductivity (0.46 mS cm −1 … Show more
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