2008
DOI: 10.1021/jp809359v
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Aligned SiC Porous Nanowire Arrays with Excellent Field Emission Properties Converted from Si Nanowires on Silicon Wafer

Abstract: Highly oriented SiC porous nanowire (NW) arrays on Si substrate have been achieved via in situ carbonizing aligned Si NW arrays standing on Si substrate. The resultant SiC NW arrays inherit the diameter and length of the mother Si NW arrays. Field emission measurements show that these oriented SiC porous NW arrays are excellent field emitter with large field emission current denstity at very low electric field. The in situ conversion method reported here might be exploited to fabricate NW arrays of other mater… Show more

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Cited by 80 publications
(51 citation statements)
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References 51 publications
(82 reference statements)
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“…In a later study [7], the field-emitting properties of oriented SiC nanowire arrays were excellent, with a lower turn-on field (0.7-1.5 V/μm), a lower threshold field (2.5-3.5 V/μm), and remarkable electron-emitting stability (24 hr of continuous operation). Excellent stability of SiCNW-based emitters has been also demonstrated in the study of Yang et al [75]. No obvious degradation of the current density (0.57 mA cm -2 ) was observed over 1200 min at an applied voltage value of 3000 V. Spanakis et al [76] presented results of the attempt to produce arrays of sharp SiC electron emitters by ultraviolet pulsedlaser processing of single-crystal SiC surfaces.…”
Section: Field Emission Cathodesmentioning
confidence: 75%
“…In a later study [7], the field-emitting properties of oriented SiC nanowire arrays were excellent, with a lower turn-on field (0.7-1.5 V/μm), a lower threshold field (2.5-3.5 V/μm), and remarkable electron-emitting stability (24 hr of continuous operation). Excellent stability of SiCNW-based emitters has been also demonstrated in the study of Yang et al [75]. No obvious degradation of the current density (0.57 mA cm -2 ) was observed over 1200 min at an applied voltage value of 3000 V. Spanakis et al [76] presented results of the attempt to produce arrays of sharp SiC electron emitters by ultraviolet pulsedlaser processing of single-crystal SiC surfaces.…”
Section: Field Emission Cathodesmentioning
confidence: 75%
“…In the drying zone, when the solvent evaporated from the solution mixtures, the structuredirecting agents formed a micellar rod and self-assembled into a hexagonal array where the silicon particles were trapped in the voids, forming silicon walls [37e39]. In the heating zone, the structure-directing agents were removed, forming a highlyordered hexagonal arrangement of mesopores, and the resulting mesoporous Si sphere frames were converted to micro and mesoporous SiC spheres by the carbonization using ethanol as the carbon source [40].…”
Section: Resultsmentioning
confidence: 99%
“…14 Previously, in depth investigations into the growth of various SiC nanostructure morphology and tailoring the bandage to lower the field emission properties have been carried out. For example, Yang et al 15 reported oriented SiC porous nanowire arrays grown at 1350 • C and obtained a turn-on field of 2.3-2.9 V/µm. Chen et al 16 reported that N doped SiC quasi aligned nanoarrays exhibited outstanding field emission properties with low turn-on field of 1.90-2.65 V/µm and threshold fields of 2.53-3.51 V/µm, respectively.…”
Section: Introductionmentioning
confidence: 99%