2017
DOI: 10.1038/s41598-017-12553-7
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Aligned hierarchical Ag/ZnO nano-heterostructure arrays via electrohydrodynamic nanowire template for enhanced gas-sensing properties

Abstract: Gas sensing performance can be improved significantly by the increase in both the effective gas exposure area and the surface reactivitiy of ZnO nanorods. Here, we propose aligned hierarchical Ag/ZnO nano-heterostructure arrays (h-Ag/ZnO-NAs) via electrohydrodynamic nanowire template, together with a subsequent hydrothermal synthesis and photoreduction reaction. The h-Ag/ZnO-NAs scatter at top for higher specific surface areas with the air, simultaneously contact at root for the electrical conduction. Besides,… Show more

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Cited by 43 publications
(31 citation statements)
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“…The addition of noble metals, such as platinum (Pt) [18], palladium (Pd) [19], gold (Au) [20], and silver (Ag) [21,22], to the metal oxide structure can increase sensitivity and the selectivity. Weber et al [19] has revealed that through spillover effect, Pd can easily enhance the response of ZnO NWs gas sensors.…”
Section: Introductionmentioning
confidence: 99%
“…The addition of noble metals, such as platinum (Pt) [18], palladium (Pd) [19], gold (Au) [20], and silver (Ag) [21,22], to the metal oxide structure can increase sensitivity and the selectivity. Weber et al [19] has revealed that through spillover effect, Pd can easily enhance the response of ZnO NWs gas sensors.…”
Section: Introductionmentioning
confidence: 99%
“…The measured S values of Pd‐ZnO with the flow rate of 100 ppm were 1.62, 0.49, and −1.82 for H 2 , CO, and NO 2 , respectively. For the Ag‐decorated ZnO, the measured S values were 0.58, 0.19, and −0.85 for H 2 , CO, and NO 2 , respectively, explained via electron transport across the interfaces between the Ag and the ZnO . In case of SnO 2 NPs, the sensitivities toward the gases were lower than those of ZnO NPs‐based sensors, may be explained by the low surface‐to‐volume ratio of the SnO 2 NPs.…”
Section: Resultsmentioning
confidence: 95%
“…The analog signals obtained in the sensors were processed by the analog-to-digital converter (ADC) of the STM32L4 microcontroller unit (MCU) to be transmitted to the main server for pattern recognition. [51] In case of SnO 2 NPs, the sensitivities toward the gases were lower than those of ZnO NPs-based sensors, may be explained by the low surface-to-volume ratio of the SnO 2 NPs. As the frequency increased to 3 Hz, the charged voltage increased to 1.71 V, enough to supply continuous power to each sensor element of the array at the same time, although there was a small reduction in the voltage when the switch to sensors was turned on (Figure 8b).…”
Section: Resultsmentioning
confidence: 96%
“…This behavior indicates that the Schottky barrier has formed at the metal-semiconductor contact. It is reported that the work function of ZnO (ϕ=5.2 eV) is larger than that of silver (ϕ=4.26 eV) [39]. Thus, the observed Schottky contact can be attributed to the differences between ZnO and Ag work functions [40].…”
Section: Optical Properties Of Zno Nanostructuresmentioning
confidence: 96%