Alcoholysis of Furfuryl Alcohol into n-Butyl Levulinate Over SBA-16 Supported Heteropoly Acid Catalyst

Sankar, Enumula Siva; Reddy, K. Saidulu; Jyothi, Y.; Raju, B. David; Rao, K. Srinivasa

doi:10.1007/s10562-017-2155-9

Cited by 39 publications

(14 citation statements)

References 34 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The transformation of abundant biomass to value added chemicals could be done either via pyrolysis, gasification or chemical/biochemical conversions. The selection of thetransformation process depends upon targeted product ,.…”

Section: Introductionmentioning

confidence: 99%

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

et al. 2018

View full text Add to dashboard Cite

With the aim of hydrogenating furfuryl alcohol into tetrahydrofurfuryl alcohol by avoiding high pressure operations and harmful solvents, a mild and sustainabable operaration is adopted. At this juncture, 1Pd/SBA15, 2Pd/SBA‐15 and 3Pd/SBA‐15 catalysts (where 1, 2 and 3 are wt% of Pd) were prepared by wet impregnation method and characterized by powder X‐ray Diffraction, N2‐physorption, Scanning Electron Microscopy, Transmission Electron Microscopy, CO‐Pulse Chemisorption, H2‐Temperature Programmed Reduction, and Inductively Coupled Plasma Optical Emission Spectroscopytechniques. Among the three catalysts, 2Pd/SBA‐15 catalyst is capable of transforming furfuryl alcohol to tetrahydrofurfuryl alcohol with nearly 100% conversion and 85% selectivity.The high surface area of SBA‐15 and high dispersion of Pd nanoparticles with large number seems to be influencing such high catalytic activity of 2Pd/SBA‐15. The 2Pd/SBA‐15 catalyst offers stable activity and selectivity during 12 h time on stream, signifying the role of support in the stabilization of Pd nano particles.

show abstract

Section: Introductionmentioning

confidence: 99%

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

et al. 2018

View full text Add to dashboard Cite

show abstract

“…With a substrate loading decrease from 1.1 to 0.3 mmol, the isopropyl levulinate yield greatly increased from 16 to 51%, likely because the number of available Brønsted acid sites to the substrate increased with the decreasing substrate loading, and the isopropyl furfuryl ether conversion to isopropyl levulinate was accelerated. 13,35…”

Section: Resultsmentioning

confidence: 99%

One-pot two-step synthesis of alkyl levulinates directly from furfural by combining Ni₃Sn₂ alloy nanoparticles and montmorillonite K10

Yamanaka

Abe

Miwaka-Saiga

et al. 2022

Sustainable Energy Fuels

View full text Add to dashboard Cite

show abstract

“…All the samples exhibit type IV isotherms with H2 hysteresis loop which is indicative of the presence of mesoporous structure with cage-like pores in accordance with the IUPAC classification and provide evidence to the retention of mesoporous structure. 20 The decrease in height of the loops with an increase in the weight loading is due to the decrease in the pore volume. 21 The structural and textural properties of the samples are presented in Table 1.…”

Section: Resultsmentioning

confidence: 99%

Ni/KIT-6 catalysts for hydrogenolysis of lignin-derived diphenyl ether

et al. 2018

View full text Add to dashboard Cite

A series of mesoporous silica KIT-6 supported Ni catalysts were prepared by wet impregnation method and evaluated for the lignin-derived diphenyl ether hydrogenolysis under atmospheric pressure in the continuous process. All the catalysts were characterized by powder XRD, N 2-physisorption, SEM, TEM, H 2-TPR analysis H 2-pulse chemisorption studies. Among the catalysts, 20-wt%-Ni/KIT-6 exhibited better activity and selectivity due to the well dispersion of Ni particles through uniform pore channel of KIT-6. 20Ni/KIT-6 shows consistent selectivity to aromatics with a decrease in conversion of diphenyl ether during the time on stream studies.

show abstract

Alcoholysis of Furfuryl Alcohol into n-Butyl Levulinate Over SBA-16 Supported Heteropoly Acid Catalyst

Cited by 39 publications

References 34 publications

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

One-pot two-step synthesis of alkyl levulinates directly from furfural by combining Ni₃Sn₂ alloy nanoparticles and montmorillonite K10

Ni/KIT-6 catalysts for hydrogenolysis of lignin-derived diphenyl ether

Contact Info

Product

Resources

About

Alcoholysis of Furfuryl Alcohol into n-Butyl Levulinate Over SBA-16 Supported Heteropoly Acid Catalyst

Cited by 39 publications

References 34 publications

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

Pd/SBA‐15 Catalysts for Hydrogenation of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol

One-pot two-step synthesis of alkyl levulinates directly from furfural by combining Ni3Sn2 alloy nanoparticles and montmorillonite K10

Ni/KIT-6 catalysts for hydrogenolysis of lignin-derived diphenyl ether

Contact Info

Product

Resources

About

One-pot two-step synthesis of alkyl levulinates directly from furfural by combining Ni₃Sn₂ alloy nanoparticles and montmorillonite K10