Al-spinels in primitive arc volcanics

Abstract

SummaryAl-rich spinels (100Cr/(Cr + A1) < 5, A1203 > 50 wt%) are common in alpine peridotites, both terrestrial and lunar marie and ultramafic cumulates, and in certain metamorphic rocks, but they are apparently rare in terrestrial volcanic rocks. Here we describe the occurrence of Al-rich spinel inclusions in olivine phenocrysts in island are volcanic rocks from five new localities: Bukit Mapas (Sumatra) and eastern Bali in the Sunda arc, and Epi, Merelava, and Ambrym islands in the Vanuatu arc. More commonly, relatively Cr-rich spinels also occur as inclusions in the same olivine phenocrysts, and it appears that the Cr-poor aluminous spinels must be in disequilibrium with the host basaltic melts. In the rocks studied, Al-rich spinels also coexist with trapped silicate glasses and highly aluminous clinopyroxene in melt inclusions in olivine. This paragenesis suggests an origin involving contamination by localised Al-rich melt pockets as opposed to a xenocrystic origin. Two mechanisms to produce this high-A1 melt in basaltic magma chambers are suggested: (1) localized high-A1 melt production by complete breakdown of assimilated lower crustal gabbroic rocks. In this model the high-A1 melt may crystallise Al-rich spinels which are subsequently trapped as solid inclusions by phenocryst phases of the host basaltic melt or may be trapped as melt inclusions in which Al-rich spinels and Al-rich clinopyroxene crystallise as daughter phases, and (2) incongruent breakdown of amphibole in amphibole-rich cumulates in sub-arc, or sub-OIB volcano magma chambers. The latter reaction produces a melt with 20-22% of A1203, aluminous clinopyroxene, Al-rich spinel and olivine. Mixing between these amphibole breakdown products and host basaltic melt may occur throughout the evolution of a magmatic system, but particularly during recharge with hot magnesian basalt batches. Aluminous spinels and aluminous clinopyroxene produced during amphibole breakdown, or perhaps crystallised from aluminous melt produced in the same reaction, are incorporated into the magma during recharge, and subsequently trapped, together with the coexisting Cr-spinels, by crystallising olivine and clinopyroxene. F. N. Della-Pasqua et al. Zusammenfassung AI-Spinelle in primitiven Inselbogen-VulkanitenAl-reiche Spinelle (100Cr/(Cr + A1) < 5, AlzO 3 > 50 Gew.~/o) sind in alpinen Peridotiten, in terrestrischen und lunaren mafischen und ultramafischen Kumulaten und in manchen metamorphen Gesteinen weit verbreitet, aber sie scheinen in terrestrischen, vulkanischen Gesteinen selten zu sein. Wir beschreiben bier das Vorkommen von A1-reichen Spinell-Inklusionen in Olivinkristallen von Inselbogen-Vulkaniten von 5 neuen Lokalit~iten: Bukit Mapas (Sumatra) und Ost-Bali im Sunda-Bogen und die Inseln Epi, Merelava und Ambrym im Vanuatu-Bogen. Relativ Cr-reiche Spindle kommen h~iufiger auch als Einschliisse in denselben Olivin-Kristallen vor, und es scheint, dab Chrom-arme Aluminiumspinelle im Ungleichgewicht mit ihren basaltischen Mutterschmelzen stehen. In den untersuchten ...

Compositional variations of chromiferous spinel in Mg-rich rocks of the Deccan Traps, India

“…These compositions are not very different from those of other spinel inclusions reported by Della-Pasqua et al (1994). The pyroxenes of D57 could be disequilibrium compositions grown in melt inclusions (cf.…”

Origin of the pleonaste-bearing mafic-ultramafic rocks from the Armutlu peninsula, NW Turkey

“…This should be related to thickness of the magmatic banding, ranging from centimeter to meter scale, and re-fertilization of magma chambers in arcrelated environments. Al-rich spinel minerals can be observed in diverse rock types and there are different arguments regarding their origins (e.g., Della-pasqua et al, 1995;Gargiulo et al, 2013). For example, the presence of Al-rich spinels in pelitic and basic-ultrabasic rocks is commonly taken as evidence for amphibolite or granulite facies metamorphism (e.g., Evans and Frost, 1975;Bucher and Frey, 2002;Rodriguez et al, 2012;Gargiulo et al, 2013).…”

“…The Al-rich spinel solid solution series have been observed in the amphibolite-granulite facies basic-ultrabasic and pelitic rocks, the basic-ultrabasic magmatic rocks, and the mantle xenoliths in volcanic rocks (e.g., Evans and Frost, 1975;Babu et al, 1997;Ho et al, 2000;Bucher and Frey, 2002;Topuz et al, 2004;Amortegui et al, 2011;Daczko et al, 2012;Rodriguez et al, 2012;Gargiulo et al, 2013). Diverse origins, such as magmatic, metamorphic, and metasomatic, have been proposed for the Al-rich spinel occurrences in these rocks (e.g., Evans and Frost, 1975;Della-Pasqua et al, 1995;Claeson, 1998;Franz and Wirth, 2000;Berger et al, 2010;Daczko et al, 2012;Gargiulo et al, 2013).…”

Geochemical and Sr–Nd isotopic variations in a deep-sea sediment core from Eastern Indian Ocean: Constraints on dust provenances, paleoclimate and volcanic eruption history in the last 300,000years

“…Ito et al, 1987;Rehka¨mper andHofmann, 1997, OIB, Indian Ocean: Hamelin et al, 1986;Barling andGoldstein, 1990, Banda &Sunda Arc Volcanics: Ben Othman et al, 1989;Della-Pasqua et al, 1995;Vroon et al, 1995;Gasparon and Varne, 1998;Handley et al, 2008;Indian Ocean Sediment: Ben Othman et al, 1989;Gasparon and Varne, 1998;Australian Continental Crust: Grousset et al, 1992;Revel-Rolland et al, 2006;Gingele et al, 2007;Carson, 2013; Nd isotopic compositions used here are Nd=10ppm, Sr=500ppm for volcanic ashes (Lytwyn et al, 2001;Turner and Foden., 2001); Nd=32ppm, Sr=100ppm for continental crust Marx et al, 2005;Gingele et al, 2007). The data plotted in the figure are also reported in Supplemental Table 3.…”