rate constants were not presented, their data are of significant interest and demonstrated increased resistance of polyethylene to scission-type reactions in the absence of oxygen.An evaluation of initial and minimum rate constants in Equation 8 for DYNH involved in this work and for constants calculated from data reported by Pardun (IS), Jellinck (79, and Tobolsky ( 1 7 ) is shown in Table I. Obviously, reaction rates, k, cannot be compared in Table I because of differences in units and differences in conditions of the degradative processes applied.However, activation energies, E, and temperature coefficients of reaction rate, k'+loc./kt, derived from ratios of reaction rates, are independent of units and can be compared. Temperature coefficients of reaction rate and activation energies of oxidation of polyethylene DYNH, Fisher-Tropsch wax, and vulcanized natural rubber are roughly comparable. Also, activation energies and frequency factors found in these specific cases are in the same order of magnitude of the values (23,000 cal. mol.-1 and 105) reported by Eyring et al. ( 2 ) for oxygen-catalyzed isomerization and polymerization of substituted ethylenes. On the other hand, polyethylene resin depolymerized in the absence of oxygen at much higher temperatures displays a higher energy of activation of scission-type degradation which is characteristic of increased stability. ACKNOWLEDGMENT Aid extended by 1,. H. Wartman and F. M. Rugg in making the reported infrared spectrophotometric measurements, and by G. A. Crowe and other associates of the author is gratefully acknowledged.