Abstract:Compared with nanoparticle‐aspect relatives titanium dioxide (TiO2), titanium‐oxo clusters (TOCs) are atomically structural‐determined and can be further precisely modified through coordination and supramolecular chemistry. Another parallel research direction is titanium‐based metal‐organic frameworks, and those based on TOC have attracted particular attention because of their high optical performances resulting from the cluster aggregation effect. Though challenging, assembling macro‐materials from specific c… Show more
Calix[n]arenes, a promising family of macrocyclic ligands, have been widely employed in the construction of polynuclear metal clusters. However, their utilization in titanium-oxo clusters (TOCs) is rare, especially in the...
Calix[n]arenes, a promising family of macrocyclic ligands, have been widely employed in the construction of polynuclear metal clusters. However, their utilization in titanium-oxo clusters (TOCs) is rare, especially in the...
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