Aggregation-Induced Emission via the Restriction of the Intramolecular Vibration Mechanism of Pinacol Lanthanide Complexes
Ju-Fen Ai,
Yun-Lan Li,
Hai-Ling Wang
et al.
Abstract:Pinacol
lanthanide complexes PyraLn (Ln
= Dy and Tb)
with the restriction of intramolecular vibration were obtained for
the first time via an in situ solvothermal coordination-catalyzed
tandem reaction using cheap and simple starting materials, thereby
avoiding complex, time-consuming, and expensive conventional organic
synthesis strategies. A high-resolution electrospray ionization mass
spectrometry (HRESI-MS) analysis confirmed the stability of PyraLn in an organic solution. The formation process of PyraLn w… Show more
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