“…Tin-sulphide complex compounds are very promising for optoelectronics, which is a consequence of high electron-phonon anharmonicity for the such kind of compounds [1]. In particular, Cu 2 ZnSnS 4 (CZTS) have attracted great attention because of its optimum direct band gap energy ($ 1.5 eV) [2], large absorption coefficient ( $ 10 4 À 6 cm À 1 ) [3], nontoxic constituent and earth abundant elements.…”