Ag2[Pd(NH3)2(SO3)2] powder

Solovyov, Leonid A.; Blokhin, A. I.; Mulagaleev, R. F.; Кирик, С. Д.

doi:10.1107/s0108270198012724

Cited by 3 publications

(1 citation statement)

References 4 publications

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“…The structures of a number of 1D, 2D and 3D μ-sulfito-metal coordination polymers have been reported. Among these are electrically neutral chains and networks, some containing only metal and sulfite as in the “binary” metal sulfites M a (SO 3 ) b , whereas in others, neutral coligands such as H 2 O, NH 3 and N-heterocycles are also bonded to the metal; there are also a few examples of anionic [M x (SO 3 ) y ] z − arrangements . In the present report, we describe the very simple generation of the Cu I (SO 3 ) 4 7− ion, in which the metal center is in a tetrahedral environment of four sulfur donors, and demonstrate that it provides a versatile building block for the construction of mixed metal 1D, 2D and 3D coordination polymers.…”

Section: Introductionmentioning

confidence: 87%

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

Abrahams

Haywood

Robson

2008

Crystal Growth & Design

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The combination of Cu(II) with excess sodium sulfite or a mixture of sodium sulfite and sodium hydrogensulfite produces a colorless solution consistent with the reduction of Cu(II) to Cu(I). The addition of divalent metal ions such as Mn 2+ , Co 2+ , Ni 2+ and Zn 2+ to such solutions, leads to the generation of coordination networks in which the divalent metal ions link together anions of formula Cu(SO 3 ) 4 7-. This symmetrical anion consists of a tetrahedrally coordinated Cu(I) center bound to the sulfur atoms of four sulfite anionic ligands. Isostructural 1D coordination polymers of composition Naand a 3D coordination polymer of composition Na(H 2 O) 6 -{[Cu I (SO 3 ) 4 ][Mn II (H 2 O) 2 ] 3 } are reported.

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Section: Introductionmentioning

confidence: 87%

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

Abrahams

Haywood

Robson

2008

Crystal Growth & Design

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ChemInform Abstract: Ag₂[Pd(NH₃)₂(SO₃)₂] Powder.

et al. 1999

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structure structure (solids and liquids) D 2000 -009-The title compound (IV) crystallizes in the monoclinic space group P2 1 /c with Z = 2. The ionic structure contains flat trans-[Pd(NH 3 ) 2 (SO 3 ) 2 ] 2− anions and Ag + cations which are tetrahedrally coordinated by oxygen atoms of the SO 3 -groups. -(SOLOVYOV, LEONID A.; BLOKHIN, ALEXANDER I.; MULAGALEEV, RUSLAN F.; KIRIK, SERGEI D.; Acta Crystallogr., Sect. C: Cryst.

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3d-Metal derivatives of the [CuI(SO3)4]7− ion: structure and magnetism

Abrahams

Haywood

et al. 2012

Dalton Trans.

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The Cu(SO(3))(4)(7-) anion, which consists of a tetrahedrally coordinated Cu(I) centre coordinated to four sulfur atoms, is able to act as a multidentate ligand in discrete and infinite supramolecular species. The slow oxidation of an aqueous solution of Na(7)Cu(SO(3))(4) yields a mixed oxidation state, 2D network of composition Na(5){[Cu(II)(H(2)O)][Cu(I)(SO(3))(4)]}·6H(2)O. The addition of Cu(II) and 2,2'-bipyridine to an aqueous Na(7)Cu(SO(3))(4) solution leads to the formation of a pentanuclear complex of composition {[Cu(II)(H(2)O)(bipy)](4)[Cu(I)(SO(3))(4)]}(+); a combination of hydrogen bonding and π-π stacking interactions leads to the generation of infinite parallel channels that are occupied by disordered nitrate anions and water molecules. A pair of Cu(SO(3))(4)(7-) anions each act as a tridentate ligand towards a single Mn(II) centre when Mn(II) ions are combined with an excess of Cu(SO(3))(4)(7-). An anionic pentanuclear complex of composition {[Cu(I)(SO(3))(4)](2)[Fe(III)(H(2)O)](3)(O)} is formed when Fe(II) is added to a Cu(+)/SO(3)(2-) solution. Hydrated ferrous [Fe(H(2)O)(6)(2+)] and sodium ions act as counterions for the complexes and are responsible for the formation of an extensive hydrogen bond network within the crystal. Magnetic susceptibility studies over the temperature range 2-300 K show that weak ferromagnetic coupling occurs within the Cu(II) containing chains of Na(5){[Cu(II)(H(2)O)][Cu(I)(SO(3))(4)]}·6H(2)O, while zero coupling exists in the pentanuclear cluster {[Cu(II)(H(2)O)(bipy)](4)[Cu(I)(SO(3))(4)]}(NO(3))·H(2)O. Weak Mn(II)-O-S-O-Mn(II) antiferromagnetic coupling occurs in Na(H(2)O)(6){[Cu(I)(SO(3))(4)][Mn(II)(H(2)O)(2)](3)}, the latter formed when Mn was in excess during synthesis. The compound, Na(3)(H(2)O)(6)[Fe(II)(H(2)O)(6)](2){[Cu(I)(SO(3))(4)](2)[Fe(III)(H(2)O)](3)(O)}·H(2)O, contained trace magnetic impurities that affected the expected magnetic behaviour.

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Ag₂[Pd(NH₃)₂(SO₃)₂] powder

Cited by 3 publications

References 4 publications

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

ChemInform Abstract: Ag₂[Pd(NH₃)₂(SO₃)₂] Powder.

3d-Metal derivatives of the [CuI(SO3)4]7− ion: structure and magnetism

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Ag2[Pd(NH3)2(SO3)2] powder

Cited by 3 publications

References 4 publications

Cu(SO3)47-: A Readily Accessible Building Block for New Coordination Polymers

Cu(SO3)47-: A Readily Accessible Building Block for New Coordination Polymers

ChemInform Abstract: Ag2[Pd(NH3)2(SO3)2] Powder.

3d-Metal derivatives of the [CuI(SO3)4]7− ion: structure and magnetism

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Ag₂[Pd(NH₃)₂(SO₃)₂] powder

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

Cu(SO₃)₄^7-: A Readily Accessible Building Block for New Coordination Polymers

ChemInform Abstract: Ag₂[Pd(NH₃)₂(SO₃)₂] Powder.