[Ag(EtOH){Ph3Bi[O(O)CC5H4N-3]2}(ClO4)]•CHCl3 – A coordination polymer based on a divergent, ditopic metalloligand
Ahmad BEN KIRAN,
Anca SILVESTRU,
Ciprian I. RAȚ
et al.
Abstract:Reaction of Ph3Bi[O(O)CC5H4N‐3]2 (1) in CHCl3 and AgClO4 in ethanol, in 1:1 molar ratio, afforded the isolation of colorless crystals of a coordination compound which was proved to be [Ag(EtOH){Ph3Bi[O(O)CC5H4N-3]2}(ClO4)]•CHCl3 (2•CHCl3) by single-crystal X-ray diffraction. A 1D coordination polymer is formed based on bridging triphenylbismuth(V) di(nicotinate) between silver atoms, with trans Ag−N dative bonds [2.183(4), 2.196(5) Å]. Additional Ag•••O interactions are established between the coinage metal at… Show more
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