2005
DOI: 10.1021/ja0558239
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AFM Single Molecule Experiments at the Solid−Liquid Interface:  In Situ Conformation of Adsorbed Flexible Polyelectrolyte Chains

Abstract: This paper reports the in situ study of conformations of flexible synthetic polymer molecules of protonated poly(2-vinylpyridine) at the solid-liquid interface at different pH of aqueous solutions. The direct conformation study of such thin ( approximately 0.4 nm) single molecules under liquid is performed for the first time. The highly protonated poly(2-vinylpyridine) chains possess a conformation of 2D equilibrated random coil, while at low degree of protonation, molecules are in the conformation of a strong… Show more

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Cited by 164 publications
(146 citation statements)
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“…(2011a) showed darker tones in order of submicrometer sizes (Ahmad et al, 2011b). Roiter and Minko (2005) reported the appearances of real linear polymer chains in liquid state on a surface as recorded using an atomic force microscope have contour length of about 204 nm (Roiter and Minko, 2005). This size might be related to the size of "bulk amorphous island" of the polymer.…”
Section: Methodsmentioning
confidence: 96%
“…(2011a) showed darker tones in order of submicrometer sizes (Ahmad et al, 2011b). Roiter and Minko (2005) reported the appearances of real linear polymer chains in liquid state on a surface as recorded using an atomic force microscope have contour length of about 204 nm (Roiter and Minko, 2005). This size might be related to the size of "bulk amorphous island" of the polymer.…”
Section: Methodsmentioning
confidence: 96%
“…They correspond to the energies needed to promote electrons from one energy level to another, higher, energy level. Atomic absorption spectrometry has many uses in different areas of chemistry [7]. Atoms of different elements absorb characteristic wavelengths of light.…”
Section: Introductionmentioning
confidence: 99%
“…The AFM was invented with the intention of revealing sample detail on the atomic level, and has reached this goal. [5][6][7] Our goal is to produce quality images on a larger scale than existing AFMs.…”
Section: Introductionmentioning
confidence: 99%