A ruthenium complex modified with (1S,2S)-1,2-diphenyl-1,2-ethanediamine efficiently catalyzes asymmetric hydrogenation of 3-chloro-1-phenylpropan-1-one in the presence of potassium hydroxide solution in isopropyl alcohol, specific optical rotation of the synthesized products reaching -24.6°. Effects of the reaction time, hydrogen pressure, and the alkali concentration on the reaction course have been elucidated.1 The text was submitted by the authors in English.Hydrogenation of carbonyl compounds has recently attracted much interest due to promising applications of the products in the field of medicine [1]. Asymmetric hydrogenation of simple ketones provides an efficient approach to prepare chiral (optically active) secondary alcohols, important organic synthesis intermediates [2].Catalytic asymmetric hydrogenation is among industrially used reactions due to its simplicity and material efficiency [3]. In particular, asymmetric hydrogenation of simple ketones occurring under mild conditions to yield chiral alcohols has received a portion of attention [4]. A number of transition-metal complexes have revealed catalytic activity towards hydrogenation of ketones; however, only rhodium and iridium complexes have efficiently catalyzed asymmetric hydrogenation with pronounced enantioselectivity [5]. A recent report has also demonstrated the potential of ruthenium complexes [6]; on top of the promising catalytic promising, ruthenium compounds are better available and cheaper than rhodium or iridium ones. Several chiral triarylphosphine ligands have been successfully applied in asymmetric hydrogenation processes [7,8].Although many highly selective chiral catalysts have been successfully used for ketones hydrogenation, their industrial applications have been complicated by requirement to remove traces of the toxic metals from the product [9]. In order to overcome the problem, catalytic asymmetric reactions catalyzed by heterogeneous catalysts have been recently investigated, heterogeneous catalysts allowing for better reaction control and being easier separated off and recycled [10].Herein, we report on preliminary studies on asymmetric hydrogenation of 3-chloro-1-phenylpropan-1-one catalyzed with γ-Al 2 O 3 -loaded DPEN-modified Ru/TPP complex [TPP standing for triphenylphosphine and DPEN standing for (1S,2S)-1,2-diphenyl-1,2-ethanediamine] [11].