Advantages and limitations of active phase silanization in <scp>PVDF</scp> composites: Focus on electrical properties and energy harvesting potential

Petrovic, M. Vijatovic; Craciun, F.; Cordero, F.; Mercadelli, E.; Ilic, N.; Despotovic, Z.; Bobic, J.; Dzunuzovic, A.; Galassi, C.; Stagnaro, P.; Canu, G.; Buscaglia, M. T.; Brunengo, E.

doi:10.1002/pc.28071

Cited by 4 publications

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Multifunctionality of MWCNT and TiC hybrid filler silicone composite for energy harvesting and strain sensing

Manikkavel,

Kumar,

Park

2024

Polymer Composites

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The flexible silicone elastomer‐conductive composite was developed with enhanced energy harvesting and strain sensing. A hybrid nanofiller system with multi‐walled carbon nanotubes (MWCNTs) and titanium (IV) carbide (TiC) was used as reinforcing agents for the elastomer. The 4 MWCNT +5 TiC composite has 1.34 MPa tensile strength, 136.85% higher than unfilled silicone rubber (SR) matrix. The unfilled sample has a 1.558 MPa compressive modulus, while 4 MWCNT +5 TiC has 3.87 MPa. The machine and finger presses were utilized to test the energy harvesting of the composite. With greater cyclic stability, the 4 MWCNT +5 TiC sample performed exceptionally well in the machine press in the output voltage range of around 120 mV. Among the thumb presses, 2 MWCNT +5 TiC yielded the best results, with a voltage of about 100 mV. The 3 MWCNT +5 TiC sample produced 9044% more energy than the single filler 3 phr MWCNT sample from our previous work. Higher MWCNT content enhanced composite stiffness, making finger pressing harder and decreasing energy output. The strain sensing test on the 4 MWCNT +5 TiC composite showed high gauge factors (GF = 7.532 and 23.944) and good linearity (R2 = 0.909 and 0.939) over a strain range of Δε = 0%–14% and 14%–22%. Silicone composites' mechanical, energy harvesting, and strain sensing performance improved greatly with the MWCNT and TiC hybrid fillers. These composites could be used in self‐powered wearable electronics, machine or structural deformation monitoring, and human motion sensing.Highlights A stretchable device was developed with improved energy harvesting and strain sensing. Rubber composites were fabricated from MWCNTs, TiC hybrid fillers, and SR matrix. The energy harvesting was 9044% higher for hybrid filler compared to MWCNT as the only filler. Robust strain sensing properties with a gauge factor of 23.9, linearity of 0.91, and relaxation time of 0.1 s. The final composites are useful for self‐powered wearable electronics, health monitoring, and human motion sensing.

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