2021
DOI: 10.3390/catal11121557
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Advances in Oxidative Desulfurization of Fuel Oils over MOFs-Based Heterogeneous Catalysts

Abstract: Catalytic oxidative desulfurization (ODS) of fuel oils is considered one of the most promising non-hydrodesulfurization technologies due to the advantages of mild reaction conditions, low cost and easy removal of aromatic sulfur compounds. Based on this reason, the preparation of highly efficient ODS catalysts has been a hot research topic in this field. Recently, metal-organic frameworks (MOFs) have attracted extensive attention due to the advantages involving abundant metal centers, high surface area, rich p… Show more

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Cited by 19 publications
(8 citation statements)
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References 123 publications
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“…In the same line, the coordinated PhC(O)S − in 9c(BF 4 ) 2 could also be hydrolyzed to generate [Zn 2 (PhBIMP)(μ-O 2 CPh)(MeCN)](BF 4 ) 2 (9f(BF 4 ) 2 ) (conversion of thiobenzoate to benzoate) while generation of hydrosulfide in the reaction solution was confirmed by precipitation of CuS. An experiment involving H 2 18 O again showed the generation of [Zn 2 (PhBIMP)(μ- 18 OOCPh)(MeCN)] 2+ (9f 18O ) by mass spectrometric analysis. All of these results indicated that the Zn(II) mediated hydrolysis of thiolates followed a mechanism similar to that proposed in Scheme 3.…”
Section: Was Essential For the Hydrolysis Reaction; (Ii) Presence Of ...mentioning
confidence: 92%
“…In the same line, the coordinated PhC(O)S − in 9c(BF 4 ) 2 could also be hydrolyzed to generate [Zn 2 (PhBIMP)(μ-O 2 CPh)(MeCN)](BF 4 ) 2 (9f(BF 4 ) 2 ) (conversion of thiobenzoate to benzoate) while generation of hydrosulfide in the reaction solution was confirmed by precipitation of CuS. An experiment involving H 2 18 O again showed the generation of [Zn 2 (PhBIMP)(μ- 18 OOCPh)(MeCN)] 2+ (9f 18O ) by mass spectrometric analysis. All of these results indicated that the Zn(II) mediated hydrolysis of thiolates followed a mechanism similar to that proposed in Scheme 3.…”
Section: Was Essential For the Hydrolysis Reaction; (Ii) Presence Of ...mentioning
confidence: 92%
“…Various semiconducting oxides, such as titanium dioxide (TiO 2 ), ZnO, CeO 2 , CdS, Fe 2 O 3 , CuO, WO 3 , Bi 2 WO 6 metal–organic frameworks, and graphene oxide (GO)–chitosan hydrogel, are used as photocatalysts for different purposes like environment, energy, solar cells, electrolysis, and chemical synthesis. Among all these semiconducting oxides, TiO 2 is largely used due to its non-toxicity, affordable cost, chemical stability, photonic activity, and low environmental impact . However, despite all these benefits, as TiO 2 has a wide band gap (3.2 eV), its photocatalytic efficiency is less in removing pollutants under different light sources.…”
Section: Introductionmentioning
confidence: 99%
“…10 Another, very famous technology is the photocatalysis process, which uses light energy to degrade pollutants. 11 A great deal of work has been performed in the past years on photocatalytic water cleaning applications. 12 However, most of the high performing photocatalytic materials are either harmful ultraviolet (UV) light active or unstable, which lose their performance within a few cycles.…”
Section: Introductionmentioning
confidence: 99%