Advances in catalytic production processes of biomass-derived vinyl monomers

Avasthi, Kalpana; Bohre, Ashish; Grilc, Miha; Likozar, Blaž; Saha, Basudeb

doi:10.1039/d0cy00598c

Cited by 25 publications

(71 citation statements)

References 238 publications

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“…Meanwhile, MOFs can not only be used directly but also can serve as templates/precursors to fabricate advanced materials. These resultant MOF‐derived materials have also attracted extensive attention because they could add diverse functional components or increase more active sites while preserving the original structure of MOFs [6–9] . To date, the popular methods employed to prepare MOF‐derivatives include high‐temperature pyrolysis, [10] chemical vapor deposition (CVD), [11] ion exchange, [12] etching, [13] and electrochemical redox [14] .…”

Section: Introductionmentioning

confidence: 99%

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

Wang

et al. 2021

ChemSusChem

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Metal‐organic framework (MOF)‐derived materials have been widely applied to diversified fields until now due to their flexible processibility. Different kinds of suitable materials can be synthesized by varying MOF templates/precursors and synthesis methods. An appropriate method can skillfully fabricate the materials with excellent performance while meeting the environmentally friendly concept. In this work, a green and flexible grinding method was introduced to synthesize MOF‐derived FeNiCo trimetallic materials without solvent‐assistance, in which Co‐ZIF‐L was selected as a sacrificial precursor and Fe3+ and Ni2+ as etchants and dopants. Surprisingly, the as‐prepared FeNiCo ternary hydroxides supported on Ni foam (G‐FeNi‐Co‐ZIF‐L/NF) showed superior electrocatalytic performance for the oxygen evolution reaction (OER) with a low overpotential of 248 mV at 10 mA cm−2. This work provides a prospective approach to synthesize various MOF‐derived multi‐metallic materials, which also opens the door for syntheses of OER electrocatalysts.

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Section: Introductionmentioning

confidence: 99%

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

Wang

et al. 2021

ChemSusChem

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“…[26,42,43] Similarly,t he production of bioethylene by sugar fermentation has ac arbon yield of 67 %. [44] On the other hand, no carbon atoms are wasted in the production of acrylate derivatives such as acrylic acid, acrolein, or acrylonitrile; [42,43,45] from as ustainability point of view,t hese are the most attractive dienophiles.…”

Section: Biobased Dienophiles:scope and Potentialmentioning

confidence: 99%

The Interplay between Kinetics and Thermodynamics in Furan Diels–Alder Chemistry for Sustainable Chemicals Production

et al. 2022

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Biomass‐derived furanic platform molecules have emerged as promising building blocks for renewable chemicals and functional materials. To this aim, the Diels–Alder (DA) cycloaddition stands out as a versatile strategy to convert these renewable resources in highly atom‐efficient ways. Despite nearly a century worth of examples of furan DA chemistry, clear structure–reactivity–stability relationships are still to be established. Detailed understanding of the intricate interplay between kinetics and thermodynamics in these very particular [4+2] cycloadditions is essential to push further development and truly expand the scope beyond the ubiquitous addend combinations of electron‐rich furans and electron‐deficient olefins. Herein, we provide pertinent examples of DA chemistry, taken from various fields, to highlight trends, establish correlations and answer open questions in the field with the aim to support future efforts in the sustainable chemicals and materials production.

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“…The objective of the present review is therefore to provide an overview of the different methodologies and strategies that have been employed to synthesize acrylates and analogs from bioresources. In order to avoid duplicity with existing literature, [ 16–25 ] herein, we will focus on the path from renewable feedstocks to the vinylic moiety of the biobased monomers ( Figure ) and the multiple molecular structures that have been obtained by different synthetic routes. We will also emphasize important advances in the polymerization of these monomers.…”

Section: Introductionmentioning

confidence: 99%

Production and Polymerization of Biobased Acrylates and Analogs

Fouilloux

Thomas

2021

Macromol. Rapid Commun.

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To prepare biobased polymers, particular attention must be paid to the obtention of the monomers from which they are derived. (Meth)acrylates and their analogs constitute such a class of monomers that have been extensively studied due to the wide range of polymers accessible from them. This review therefore aims to highlight the progresses made in the production and polymerization of (meth)acrylates and their analogs. Acrylic acid production from biomass is close to commercialization, as three different high‐potential intermediates are identified: glycerol, lactic acid, and 3‐hydroxypropionic acid. Biobased methacrylic acid is less common, but several promising options are available, such as the decarboxylation of itaconic acid or the dehydration of 2‐hydroxyisobutyric acid. Itaconic acid is also a vinylic monomer of great interest, and polymers derived from it have already found commercial applications. Methylene butyrolactones are promising monomers, obtained from bioresources via three different intermediates: levulinic, succinic, or itaconic acid. Although expensive, methylene butyrolactones have a strong potential for the production of high‐performance polymers. Finally, β‐substituted acrylic monomers, such as cinnamic, fumaric, muconic, or crotonic acid, are also examined, as they provide an original access to biobased materials from various renewable raw materials, such as protein waste, lignin, or wastewater.

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Advances in catalytic production processes of biomass-derived vinyl monomers

Abstract:
Plastics industry technologies currently source the majority of monomers from crude oil substances. Although we have witnessed a significant companies’ interest towards the utilization of the sustainable feedstock materials for...

Cited by 25 publications

References 238 publications

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

The Interplay between Kinetics and Thermodynamics in Furan Diels–Alder Chemistry for Sustainable Chemicals Production

Production and Polymerization of Biobased Acrylates and Analogs

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Advances in catalytic production processes of biomass-derived vinyl monomers

Abstract: Plastics industry technologies currently source the majority of monomers from crude oil substances. Although we have witnessed a significant companies’ interest towards the utilization of the sustainable feedstock materials for...

Cited by 25 publications

References 238 publications

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

Synthesis of FeNiCo Ternary Hydroxides through Green Grinding Method with Metal‐Organic Frameworks as Precursors for Oxygen Evolution Reaction

The Interplay between Kinetics and Thermodynamics in Furan Diels–Alder Chemistry for Sustainable Chemicals Production

Production and Polymerization of Biobased Acrylates and Analogs

Contact Info

Product

Resources

About

Abstract:
Plastics industry technologies currently source the majority of monomers from crude oil substances. Although we have witnessed a significant companies’ interest towards the utilization of the sustainable feedstock materials for...