Advances and prospects of porphyrin derivatives in the energy field

Xie, Mingfa; Liu, Jinyuan; Dai, Lianghong; Peng, Hongjian; Xie, Youqing

doi:10.1039/d3ra04345b

Cited by 5 publications

(3 citation statements)

References 172 publications

(219 reference statements)

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“…CDCA is a recognized de-aggregating agent commonly employed in DSSC. The incorporation of CDCA as a co-adsorber in DSSC has been shown to enhance cell performance by influencing the photocurrent through increased charge collection and/or electron injection, as well as by improving open-circuit photovoltage through the suppression of charge recombination [ 37 , 38 , 39 , 40 ].…”

Section: Resultsmentioning

confidence: 99%

Synthesis and Photovoltaic Performance of β-Amino-Substituted Porphyrin Derivatives

Cerqueira,

Pinto,

Malta

et al. 2024

IJMS

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New β-amino-substituted porphyrin derivatives bearing carboxy groups were synthesized and their performance as sensitizers in dye-sensitized solar cells (DSSC) was evaluated. The new compounds were obtained in good yields (63–74%) through nucleophilic aromatic substitution reactions with 3-sulfanyl- and 4-sulfanylbenzoic acids. Although the electrochemical studies indicated suitable HOMO and LUMO energy levels for use in DSSC, the devices fabricated with these compounds revealed a low power conversion efficiency (PCE) that is primarily due to the low open-circuit voltage (Voc) and short-circuit current density (Jsc) values.

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Section: Resultsmentioning

confidence: 99%

Synthesis and Photovoltaic Performance of β-Amino-Substituted Porphyrin Derivatives

Cerqueira,

Pinto,

Malta

et al. 2024

IJMS

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“…1,2 Porphyrins possess exceptional characteristics, including optical, magnetic, redox, and photophysical properties, making them highly valuable for a wide range of applications. Chemically modied porphyrins with different functionalities can be tailored for use in solar cells, 3,4 sensors, 5,6 medical imaging, 7,8 photodynamic therapy, [9][10][11] supercapacitors, 1,12,13 and other applications. Porphyrins are characterized by their highly stable aromatic macrocyclic nature, abundant nitrogen atoms, and an extensive p-conjugated system.…”

Section: Introductionmentioning

confidence: 99%

An ambipolar PEDOT-perfluorinated porphyrin electropolymer: application as an active material in energy storage systems

Bermúdez Prieto,

González López,

Solis

et al. 2024

RSC Adv.

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“…[24,25] Zinc porphyrins are the most studied class of porphyrin materials, which are widely studied and applied in dye-sensitized solar cells, organic and perovskite hybrid solar cells. [26,27] It was shown that complexes of other metals with porphyrins, [28,29] including manganese complexes, [30][31][32] are also promising components for energy-related applications. One of the recent studies has shown that significant enhancement of the stabilized power conversion efficiency was recorded by 22 % [30] by combining Mn porphyrin and CH 3 NH 3 PbI 3 perovskite.…”

Section: Introductionmentioning

confidence: 99%

Axial Coordinated Manganese(III) Porphyrin/Tetraazaporphyrin – 4‐(10‐phenylanthracen‐9‐yl)Pyridine Dyads: Self‐Assembly, Structure and Spectral Properties in Ground and Excited States

Ovchenkova,

Tsaturyan,

Bichan

et al. 2024

Chemistry An Asian Journal

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Self‐assembly of new donor‐acceptor systems based on (5,10,15,20‐tetraphenylporphinato)manganese(III)/(5,10,15,20‐tetra‐4‐tert‐butylphenylporphinato)manganese(III)/(octakis(4‐tert‐butylphenyl)tetraazaporphinato)manganese(III) acetate ((AcO)MnTPP/(AcO)MnTBPP/(AcO)MnTAP) and 4‐(10‐phenylanthracen‐9‐yl)pyridine (PyAn) was studied using fluorescence spectroscopy and mass spectrometry. It was found that the coordination complexes of 1:1 composition (dyads) are formed in toluene. The spectral properties, the chemical structures and redox behavior of the dyads were described using 1H NMR, IR, EPR spectroscopy and cyclic voltammetry, respectively. The dynamic processes and the characteristics in the excited state of the dyads were obtained using the femtosecond transient absorption spectroscopy method. Density functional theory (DFT), time‐dependent DFT methods were used to elucidate the dyad electronic structures and to establish the differences in their frontier molecular orbitals. The analysis of the lambda parameter and the distance of hole‐pair interaction was indicated more favorable charge transfer between the macrocycle and the axial PyAn fragment in (AcO)(PyAn)MnTAP. The calculated values of the zero‐field splitting parameters D and E/D, together with the g tensors of the lowest spin‐orbit state for (AcO)MnTPP and (AcO)(PyAn)MnTPP were obtained using the combination of DFT and Multireference Perturbation Theory (CASSCF/NEVPT2) simulations. The data obtained develop the fundamental basis in the field of photovoltaics and show the prospects for the study of molecular systems of this class.

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Advances and prospects of porphyrin derivatives in the energy field

Cited by 5 publications

References 172 publications

Synthesis and Photovoltaic Performance of β-Amino-Substituted Porphyrin Derivatives

Synthesis and Photovoltaic Performance of β-Amino-Substituted Porphyrin Derivatives

An ambipolar PEDOT-perfluorinated porphyrin electropolymer: application as an active material in energy storage systems

Axial Coordinated Manganese(III) Porphyrin/Tetraazaporphyrin – 4‐(10‐phenylanthracen‐9‐yl)Pyridine Dyads: Self‐Assembly, Structure and Spectral Properties in Ground and Excited States

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