“…138 The modification of an amorphous phase with a large number of dangling bonds and unsaturated surface atoms can provide adsorption sites for reactants, which are also beneficial for the enrichment of reaction intermediates. 139 Wan et al demonstrated that delocalized protons generated at the amorphous NiO x H y shell could easily cascade inward to the interface Pt sites through hydrogen bonding networks, improving the effective proton supply rate on the Pt surface for later Tafel steps (Fig. 8g–i).…”
Section: Engineering the Surface Microenvironment Of Electrocatalystsmentioning
Electrocatalytic water splitting reaction kinetics are usually determined by the intrinsic activity of electrocatalyst and the microenvironment at the electrode-electrolyte interface. Compared to electronic structure regulation based on intrinsic activity,...
“…138 The modification of an amorphous phase with a large number of dangling bonds and unsaturated surface atoms can provide adsorption sites for reactants, which are also beneficial for the enrichment of reaction intermediates. 139 Wan et al demonstrated that delocalized protons generated at the amorphous NiO x H y shell could easily cascade inward to the interface Pt sites through hydrogen bonding networks, improving the effective proton supply rate on the Pt surface for later Tafel steps (Fig. 8g–i).…”
Section: Engineering the Surface Microenvironment Of Electrocatalystsmentioning
Electrocatalytic water splitting reaction kinetics are usually determined by the intrinsic activity of electrocatalyst and the microenvironment at the electrode-electrolyte interface. Compared to electronic structure regulation based on intrinsic activity,...
“…2d). 62–64 Besides, each step of the AEM involves an electron–proton transfer process, causing OER activities being pH-independent. 65 Meanwhile, catalysts undergoing the AEM pathway usually display excellent stability during the OER process.…”
As one promising technology for highly pure hydrogen production under mild conditions, electrochemical water splitting has been garnering substantial interest, while its efficiency and rate are primarily restricted by the...
“…8,9 Among these, electrocatalysts have garnered significant attention and are widely studied. 10–13 Strategies to enhance their electrocatalytic performance are rapidly expanding, such as doping, atomic dispersion, nanostructures, and heterointerface engineering, all of which show effective utilization of the intrinsic atoms involved. It makes a significant contribution to the activity and selectivity of electrocatalysts.…”
The conversions of carbon resource, such as alcohols, aldehydes/ketones, and ethers have been being one of the hottest topics most recently for the goal of carbon neutralization. The emerging electrocatalytic...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.