Advanced fuel-cell development. Progress report, January-March 1982. [Molten carbonate fuel cells]

Pierce, R.D.; Arons, R. M.; Briendel, A.M.; Kucera, G.H.; Sim, J. W.; Smith, J. L.; Stapay, J.R.

doi:10.2172/5630165

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“…Many attempts have been made to increase the thermodynamic stability of the NiO cathode in the carbonate melt. [1][2][3][4][5][6] The easiest way is to introduce modifications into the best of the existing materials so as to improve certain characteristics. Thus, by making use of the good electrical conductivity and catalytic activity of lithiated NiO, it may be of value to increase the stability of NiO in the melt by alloying the Ni components.…”

Section: Introductionmentioning

confidence: 99%

Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C

Zeng¹,

Zhou²,

Wu³

2004

Corrosion Engineering, Science and Technology

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The effect of pre-oxidation treatment at 650uC in air on the corrosion behaviour of binary Ni-Ti alloys containing 5, 10, and 15 wt-%Ti in eutectic (Li, K) 2 CO 3 at 650uC in air has been investigated. The results indicate that the pre-oxidation of the alloys can produce an almost pure TiO 2 scale. Nevertheless, this TiO 2 scale cannot hinder the formation of NiO outside and beneath the TiO 2 scale during subsequent molten salt corrosion. The corrosion rates of the alloys decrease with increasing content of titanium in the alloys. The corrosion of the alloys proceeds mainly by inward diffusion of oxygen through the TiO 2 layer, forming large quantities of NiO beneath the TiO 2 layer. Compared with Ni-5Ti and Ni-10Ti, the formation of NiO on Ni-15Ti is inhibited significantly, especially in the initial stages.CEST/2033

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Section: Introductionmentioning

confidence: 99%

Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C

Zeng¹,

Zhou²,

Wu³

2004

Corrosion Engineering, Science and Technology

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show abstract

Advanced fuel-cell development. Progress report, January-March 1982. [Molten carbonate fuel cells]

Cited by 1 publication

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Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C

Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C

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Advanced fuel-cell development. Progress report, January-March 1982. [Molten carbonate fuel cells]

Cited by 1 publication

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Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)2CO3mixture at 650°C

Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)2CO3mixture at 650°C

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Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C

Effect of pre-oxidation treatment on the corrosion behaviour of Ni–Ti alloys in eutectic (Li, K)₂CO₃mixture at 650°C