Advanced Formulations Based on Poly(ionic liquid) Materials for Additive Manufacturing

Miralles-Comins, Sara; Zanatta, Marcileia; Sans, Víctor

doi:10.3390/polym14235121

Cited by 13 publications

(13 citation statements)

References 248 publications

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“…Table highlights a variety of reviews focusing on applications of PILs in energy materials, devices, and biomedical materials. 29, 33, 38, − ,,, The types of the applications we discuss here are summarized in Figure . Alphabetically, these application areas include: 3D printing, adhesion; antimicrobial materials; antifouling coatings; catalysis and catalysts; conductive electrolytes; devices; electromagnetic shielding; emulsions and dispersions; coatings; energy storage and conversions; PIL derivatives; sensors; and actuators., and self-healing materials.…”

Section: Applicationsmentioning

confidence: 99%

“…Table 1 highlights a variety of reviews focusing on applications of PILs in energy materials, devices, and biomedical materials. 29,33,38,[43][44][45]56,59,62 The types of the applications we discuss here are summarized in Figure 28.…”

Section: Applicationsmentioning

confidence: 99%

“…787 Combined with 3D printing technology, the physicochemical properties of ILs/PILs can be greatly enhanced. Early applications from Long and coworkers 788 have steadily increased in number and diversity, and a recent review has been provided by Miralles-Comins et al 62 Brief summaries illustrating recent applications of PILs in 3D printing are listed in Table 14.…”

Section: D Printingmentioning

confidence: 99%

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Polymerized and Colloidal Ionic Liquids─Syntheses and Applications

Li,

Yan,

Texter

2024

Chem. Rev.

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The breadth and importance of polymerized ionic liquids (PILs) are steadily expanding, and this review updates advances and trends in syntheses, properties, and applications over the past five to six years. We begin with an historical overview of the genesis and growth of the PIL field as a subset of materials science. The genesis of ionic liquids (ILs) over nano to meso lengthscales exhibiting 0D, 1D, 2D, and 3D topologies defines colloidal ionic liquids, CILs, which compose a subclass of PILs and provide a synthetic bridge between IL monomers (ILMs) and micro to macroscale PIL materials. The second focus of this review addresses design and syntheses of ILMs and their polymerization reactions to yield PILs and PIL-based materials. A burgeoning diversity of ILMs reflects increasing use of nonimidazolium nuclei and an expanding use of step-growth chemistries in synthesizing PIL materials. Radical chain polymerization remains a primary method of making PILs and reflects an increasing use of controlled polymerization methods.Step-growth chemistries used in creating some CILs utilize extensive cross-linking. This cross-linking is enabled by incorporating reactive functionalities in CILs and PILs, and some of these CILs and PILs may be viewed as exotic cross-linking agents. The third part of this update focuses upon some advances in key properties, including molecular weight, thermal properties, rheology, ion transport, self-healing, and stimuli-responsiveness. Glass transitions, critical solution temperatures, and liquidity are key thermal properties that tie to PIL rheology and viscoelasticity. These properties in turn modulate mechanical properties and ion transport, which are foundational in increasing applications of PILs. Cross-linking in gelation and ionogels and reversible step-growth chemistries are essential for self-healing PILs. Stimuli-responsiveness distinguishes PILs from many other classes of polymers, and it emphasizes the importance of segmentally controlling and tuning solvation in CILs and PILs. The fourth part of this review addresses development of applications, and the diverse scope of such applications supports the increasing importance of PILs in materials science. Adhesion applications are supported by ionogel properties, especially crosslinking and solvation tunable interactions with adjacent phases. Antimicrobial and antifouling applications are consequences of the cationic nature of PILs. Similarly, emulsion and dispersion applications rely on tunable solvation of functional groups and on how such groups interact with continuous phases and substrates. Catalysis is another significant application, and this is an historical tie between ILs and PILs. This component also provides a connection to diverse and porous carbon phases templated by PILs that are catalysts or serve as supports for catalysts. Devices, including sensors and actuators, also rely on solvation tuning and stimuliresponsiveness that include photo and electrochemical stimuli. We conclude our view of applications with 3D printi...

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Section: Applicationsmentioning

confidence: 99%

Section: Applicationsmentioning

confidence: 99%

Section: D Printingmentioning

confidence: 99%

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Polymerized and Colloidal Ionic Liquids─Syntheses and Applications

Li,

Yan,

Texter

2024

Chem. Rev.

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“…These properties make PILs attractive for innovative applications in catalysis, 189,221 such as the generation of catalytic devices by 3D printing. 191,222…”

Section: Polymeric Ils (Pils)mentioning

confidence: 99%

“…PILs have a variety of properties, including ionic conductivity, hydrophilicity, hydrophobicity, chemical durability, and thermodynamic stability. These properties make PILs attractive for innovative applications in catalysis, , such as the generation of catalytic devices by 3D printing. , …”

Section: Ils Properties As Media and Support For Catalysismentioning

confidence: 99%

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

Dupont,

Leal,

Lozano

et al. 2024

Chem. Rev.

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DLP‐Printable Porous Cryogels for 3D Soft Tactile Sensing

Cafiso,

Bernabei,

Lo Preti

et al. 2024

Adv Materials Technologies

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Three‐Dimensional (3D) printed porous materials hold the potential for various soft sensing applications due to their remarkable flexibility, low density, and customizable geometries. However, developing versatile and efficient fabrication methods is crucial to unlock their full potential. A novel approach is introduced by combining Digital Light Processing (DLP) 3D printing and freeze‐drying to manufacture deformable cryogels featuring intricate morphologies. Photocurable hydrogels based on Poly(3,4‐ethylenedioxythiophene)Polystyrene sulfonate (PEDOT:PSS), Polyethylene glycol Diacrylate (PEGDA) and Ethylene Glycol (EG) are successfully printed and lyophilized. In this way, porous cryogels with tailorable properties are achieved. Microporosity varies from 68% to 96%, according to the chemical composition. Ultra‐soft cryogels with a compressive modulus of 0.13MPa are fabricated by adding a reactive diluent. As a result of the cryogelation process, which effectively removes water from the hydrogels, microporous structures with details as fine as 100 µm are obtained. The achieved freedom of design is exploited to fabricate resistive force sensors with a honeycomb lattice morphology. The sensitivity and the working range of the sensors can be tailored by tuning the size of the cells, paving the way for sensors with programmable architectures that can meet diverse requirements.

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Advanced Formulations Based on Poly(ionic liquid) Materials for Additive Manufacturing

Cited by 13 publications

References 248 publications

Polymerized and Colloidal Ionic Liquids─Syntheses and Applications

Polymerized and Colloidal Ionic Liquids─Syntheses and Applications

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

DLP‐Printable Porous Cryogels for 3D Soft Tactile Sensing

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