Advanced Electrode Materials for Potassium‐Ion Hybrid Capacitors

Abstract

Potassium‐ion hybrid capacitors (PIHCs) overcome the limitations of potassium‐ion batteries (PIBs) and supercapacitors (SCs) and integrate the advantages of both, including high energy density, high power density, low cost, long cycle life, and stable electrochemical performance. However, the development of PIHCs is hindered by thermodynamic instability and kinetic hysteresis. Additionally, the dynamic mismatch between anode and cathode materials poses an urgent challenge. To this end, many research works related to material development have been dedicated to overcoming the drawbacks. In this review, the energy storage mechanism of PIHCs is briefly introduced. Moreover, the research progress and achievements of anode and cathode materials in recent years are reviewed, including carbon‐based materials, MXenes, transition metal materials, Prussian blue and its analogues. Finally, the challenges and prospects of PIHCs are proposed, together with guiding significant research directions in the future.

A high performance and long-cycling bi-functional carbon electrode derived from Phyllanthus emblica (amla) for potassium ion batteries and supercapacitors

“…, have been utilized. 20–22 Among these materials, carbon-based anodes, primarily including hard carbon, carbon nanotubes, graphite, and mesocarbon microspheres, are considered the most potential candidates for K-ion batteries and supercapacitors due to their low cost, environmental friendliness, and excellent performance. 23–30…”

Enhanced As-COF nanochannels as a high-capacity anode for K and Ca-ion batteries

“…These intrinsic benefits have prompted much investigation into possible materials for KIB electrodes. 7 Concurrently, there has been a great deal of interest in multivalent ion batteries (MIBs), which use ions like calcium (Ca 2+ ), magnesium (Mg 2+ ), and aluminum (Al 3+ ) that have many valence states. MIBs promise higher energy density due to multiple electron transfers per ion.…”