Green, efficient and sustainable treatment of secondary
resources
such as electronic waste (e-waste) has significant strategic, economic
and environmental value for the future social development, but it
remains a serious task. Here, an intelligent yolk–shell-structured
ion-imprinted magnetic mesoporous nanorobot (MMNR-IIP-YS) was assessed
for rapid and selective gold stripping from leaching solutions from
e-waste leachates and employed for water decontamination by targeting
organic contaminants. MMNR-IIP-YS exhibited a competitive adsorption
capacity (65.01 mg g–1) which was 2.69 times that
of the non-imprinted polymer (24.16 mg g–1) at 298
K and possesses superior adsorption rate, excellent selectivity, long-term
stability, and recycling ability. Interestingly, a closed-loop miniplant
was established for sustainable treatment of e-waste, revealing that
MMNR-IIP-YS was capable of extracting 98.51% of gold from actual waste
leachates and showing efficient and stable degradation efficiency
of toxic organics and dyes. These findings have the potential for
application in industrial-scale treatment of e-waste and suggest an
appealing strategy based on self-propelled nanorobots for future development
of sustainable waste utilization systems.