2017
DOI: 10.1016/j.cej.2016.11.067
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Adsorptive desulfurization using Cu–Ce/metal–organic framework: Improved performance based on synergy between Cu and Ce

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Cited by 91 publications
(52 citation statements)
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“…There is great potential in using adsorbents for deep desulfurization, because organic sulfur molecules can be captured at ambient conditions with high efficiency (Song et al, 2014;Vilarrasa-Garcia et al, 2011b;Xiong et al, 2010). It is commonly known that both p complexation and direct sulfur metal (S-M) bonds can work for adsorptive desulfurization (Danmaliki and Saleh, 2017;Khan et al, 2017;Shi et al, 2017Song et al, 2013. Thus, active species, such as Cu 2 O (Jiang et al, 2013;Wang et al, 2009b), CeO 2 Xiao et al, 2013a), etc.…”
Section: Introductionmentioning
confidence: 99%
“…There is great potential in using adsorbents for deep desulfurization, because organic sulfur molecules can be captured at ambient conditions with high efficiency (Song et al, 2014;Vilarrasa-Garcia et al, 2011b;Xiong et al, 2010). It is commonly known that both p complexation and direct sulfur metal (S-M) bonds can work for adsorptive desulfurization (Danmaliki and Saleh, 2017;Khan et al, 2017;Shi et al, 2017Song et al, 2013. Thus, active species, such as Cu 2 O (Jiang et al, 2013;Wang et al, 2009b), CeO 2 Xiao et al, 2013a), etc.…”
Section: Introductionmentioning
confidence: 99%
“…According to the literature, 22 the absence of peaks at about 932 eV was characteristic of the reduced copper species, which included Cu 0 and Cu + . Khan et al 23 attributed the peak at about 932 eV to the presence of Cu + . However, Chen et al 24 reported that Cu + was only the intermediate transition state, which was beneficial for promoting the conversion of Cu 2+ to Cu 0 at high temperatures.…”
Section: Resultsmentioning
confidence: 99%
“…The adsorption results were analyzed with a pseudo-second-order non-linear kinetic model [69], Langmuir isotherm [70], and separation factor [71]. The effect of pH on DUR and 2,4-D adsorption over IMDC was studied by adjusting the solution pH by adding small amounts of 0.1 M HCl or NaOH solutions.…”
Section: Adsorption Experimentsmentioning
confidence: 99%
“…The rapid adsorption of both adsorbates over IMDC suggests that specific interactions occur between IMDC and the adsorbates. The maximum adsorption capacities (Q 0 ) and b-values of the studied adsorbents were calculated from their corresponding Langmuir plots [70,75] (shown in Fig. S1) and are summarized in Table 4.…”
Section: Comparison Of Adsorbents and Adsorption Kineticsmentioning
confidence: 99%