Adsorption separation of carbon dioxide from flue gas of natural gas-fired boiler by a novel nanoporous “molecular basket” adsorbent

Xu, Xin; Song, Chunshan; Miller, Bruce G.; Scaroni, Alan W.

doi:10.1016/j.fuproc.2005.01.002

Cited by 283 publications

(248 citation statements)

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“…Therefore its application in large scale sources is limited. Recently, the newest type of adsorbents like "molecular basket" and "molecular cages" were synthesized and studied in the aspect of the CO 2 capture [27][28][29][30], and also the promising carbon based "molecular basket" sorbents with high CO 2 sorption capacity were also developed [31].…”

Section: Introductionmentioning

confidence: 99%

Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve

Nuermaiti¹,

Li²

2017

AJCHE

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Abstract:The adsorption equilibria of pure supercritical N 2 and CO 2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 were measured by the gravimetric method (IGA-001, Hiden) in the temperature region of 313.15-393.15 K and pressure region of 0-2 MPa. The adsorption kinetics of N 2 and of CO 2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 at 313.15 K in 50 kPa were tested. The Langmuir-Freundlich model was applied to analyze the adsorption isotherms. The adsorption kinetics was investigated with the Fickian model. The analysis of adsorption equilibria showed that a high temperature, low pressure is beneficial to the equilibria based selective adsorption of supercritical CO 2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200. The investigation of adsorption kinetics exposed that the carbon molecular sieve CMS-200 is able to separate CO 2 from the N 2 /CO 2 mixture by its kinetic effect, and lower temperature is preferred.

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Section: Introductionmentioning

confidence: 99%

Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve

Nuermaiti¹,

Li²

2017

AJCHE

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“…In addition, the basicity of liquid alkanolamine leads to severe corrosion of equipments and peripheral pipelines [2]. Besides, this approach required large equipments size, which is suffer from solvent leakage and corrosion problem [18][19].…”

Section: Introductionmentioning

confidence: 99%

“…Solid CO 2 adsorption processes require less space and lower energy, cost effective and easy to handle in a wide range of temperature and pressure [16,[18][19][20][21][22]. Moreover, this alternative approach offers few advantages such as less toxic, non corrosive nature [23] and high CO 2 capacity captured.…”

Section: Introductionmentioning

confidence: 99%

“…This new type of sorbent for CO 2 adsorption should has a porous structure of solid supports to be filled with amine compounds to enable the retention of CO 2 molecules. Commonly used porous solid supports are silica fume [2], zeolite [4], mesoporous silica [8,13,20], high-carbon fly ash [18], activated carbon [27] and hydrotalcyte [28]. However, solid sorbents prepared with amorphous silica [12,20] and octadecylamine (ODA) for CO 2 capture are still limited.…”

Section: Introductionmentioning

confidence: 99%

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Adsorption of CO2 on silica dioxide catalyst impregnated with various alkylamine

Tahari

Yarmo

2014

AIP Conference Proceedings

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Abstract. Silica dioxide catalyst (SiO 2 ) can be modified by impregnating amine-containing compounds to improve the CO 2 adsorption capacity. Four type of amines, i.e., monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA) and octadecylamine (ODA) were supported on silica dioxide particles. The amine-modified samples were characterized using FTIR, BET and FESEM. All the prepared solid sorbents exhibited type IV isotherm with hysteresis loop. Specific surface areas of the sorbents were significantly reduced due to blocking of micropores and mesopores by the amine compounds. Reactivity of solid sorbents towards CO 2 was evaluated using isothermal CO 2 adsorption by BET. CO 2 adsorption capacity increased with the weight percent of amine compounds loaded onto the SiO 2 . 15 and 25 wt % MEA/SiO 2 and 25 wt % ODA/SiO 2 sorbents showed greater CO 2 adsorption capacities compared to the virgin sample (SiO 2 ). This study shows that the order of adsorption capacity for the four types of amines was MEA (4.05 wt % CO 2 /adsorbent) > ODA (2.45 wt % CO 2 /adsorbent) > DEA (1.71 wt % CO 2 /adsorbent) > TEA (0.91 wt % CO 2 /adsorbent). CO 2 uptakes by ODA/SiO 2 sorbents were higher than DEA/SiO 2 and TEA/SiO 2 is mainly due to their smaller pore volume and pore width of the adsorbent, therefore, greater interactions of CO 2 -ODA in pores. MEA/SiO 2 has the highest ability in capturing CO 2 because of the increasing steric hindrance of long chain ODA and alkyl substituent on DEA and TEA.

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“…3 The positive effect of moisture on the capacity of amine functionalized sorbents has been contributed to the formation of bicarbonate in the presence of moisture. 13,14,33,34 The effect of the adsorption temperature on capture capacity was investigated using 1 atm dry CO 2 . As shown in Fig.…”

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Mesoporous amine‐bridged polysilsesquioxane for CO₂ capture

Duan

et al. 2011

Greenhouse Gases

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a novel class of amine-supported sorbents based on amine-bridged mesoporous polysilsesquioxane was developed via a simple one-pot sol-gel process. The new sorbent allows the incorporation of a large amount of active groups without sacrificing surface area or pore volume available for CO 2 capture, leading to a CO 2 capture capacity of 3.2 mmol g -1 under simulated flue gas conditions. The sorbent is readily regenerated at 100 °C and exhibits good stability over repetitive adsorption-desorption cycling.

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Adsorption separation of carbon dioxide from flue gas of natural gas-fired boiler by a novel nanoporous “molecular basket” adsorbent

Cited by 283 publications

References 12 publications

Supercritical Adsorption Based CO<sub>2</sub> Capture from N<sub>2</sub>/CO<sub>2</sub> Mixture by Activated Carbon and Carbon Molecular Sieve

Supercritical Adsorption Based CO<sub>2</sub> Capture from N<sub>2</sub>/CO<sub>2</sub> Mixture by Activated Carbon and Carbon Molecular Sieve

Adsorption of CO2 on silica dioxide catalyst impregnated with various alkylamine

Mesoporous amine‐bridged polysilsesquioxane for CO₂ capture

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Adsorption separation of carbon dioxide from flue gas of natural gas-fired boiler by a novel nanoporous “molecular basket” adsorbent

Cited by 283 publications

References 12 publications

Supercritical Adsorption Based CO&lt;sub&gt;2&lt;/sub&gt; Capture from N&lt;sub&gt;2&lt;/sub&gt;/CO&lt;sub&gt;2&lt;/sub&gt; Mixture by Activated Carbon and Carbon Molecular Sieve

Supercritical Adsorption Based CO&lt;sub&gt;2&lt;/sub&gt; Capture from N&lt;sub&gt;2&lt;/sub&gt;/CO&lt;sub&gt;2&lt;/sub&gt; Mixture by Activated Carbon and Carbon Molecular Sieve

Adsorption of CO2 on silica dioxide catalyst impregnated with various alkylamine

Mesoporous amine‐bridged polysilsesquioxane for CO2 capture

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Product

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Supercritical Adsorption Based CO<sub>2</sub> Capture from N<sub>2</sub>/CO<sub>2</sub> Mixture by Activated Carbon and Carbon Molecular Sieve

Supercritical Adsorption Based CO<sub>2</sub> Capture from N<sub>2</sub>/CO<sub>2</sub> Mixture by Activated Carbon and Carbon Molecular Sieve

Mesoporous amine‐bridged polysilsesquioxane for CO₂ capture