Adsorption of pyrolysis oil model compound (phenol) with plasma-modified hydro-chars and mechanism exploration

Abstract

Phenol is one of the important ingredients of pyrolysis oil, contributing to the high biotoxicity of pyrolysis oil. To promote the degradation and conversion of phenol during anaerobic digestion, hydro-chars with high phenol adsorption capacity were produced. The phenol adsorption capabilities of the plain hydrochar, plasma modi ed hydro-char at 25 ℃ (HC-NH 3 -P-25), and plasma modi ed hydro-char at 500 ℃ (HC-NH 3 -P-500), and their adsorption kinetics and thermodynamics were explored. Experimental results indicate that the phenol adsorption capability of HC-NH 3 -P-500 was the highest. The phenol adsorption kinetics of all samples followed the Pseudo-second-order equation and interparticle diffusion model, indicating that the adsorption rate of phenol was controlled by interparticle diffusion and chemistry adsorption simultaneously. By DFT calculations, π-π stacking and hydrogen bond are the main interactions for phenol adsorption. It was observed that an enriched graphite N content decreased the average vertical distance between hydro-chars and phenol in π-π stacking complex, from 3.5120 Å to 3.4532 Å, causing an increase in the negative adsorption energy between phenol and hydro-char from 13.9330 to 23.4181 kJ/mol. For hydrogen bond complex, the average vertical distance decreased from 3.4885 Å to 3.3386 Å due to the increase in graphite N content; causing the corresponding negative adsorption energy increased from 19.0233 to 19.9517 kJ/mol. Additionally, the presence of graphite N in the hydro-char created a positive diffusion region and enhanced the electron density between hydro-char and phenol. Analyses suggest that enriched graphite N contributed to the adsorption complex stability, resulting in an improved phenol adsorption capacity. HighlightsHydro-chars modi ed with plasmas at 500 ℃ exhibits the largest phenol removal rateThe highest N doping in hydro-char achieved at 500 ℃ modi cation Plasma-doped N in hydro-chars is mainly graphite N and pyridine N Increase in graphite N is bene cial for the phenol adsorption Adsorption force for phenol mainly consists of π-π stacking and hydrogen bond