2023
DOI: 10.1039/d3ra05347d
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Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles

Anastassiya A. Mashentseva,
Nurzhigit Seitzhapar,
Murat Barsbay
et al.

Abstract: This study investigates the sorption removal of lead(ii) ions using zinc oxide (ZnO) and copper(ii) oxide (CuO) nanoparticles synthesized through a wet combustion synthesis with the aid of plant extract from Serratula coronata L.

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Cited by 8 publications
(5 citation statements)
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References 98 publications
(131 reference statements)
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“…The mechanism underlying these observations can be attributed to the interplay between pH and the surface charge of the adsorbents. At a lower pH (pH 3), the surface of the nanocomposite beads may carry a net positive charge, which is less favorable for the adsorption of paracetamol, given its predominantly negative charge [ 38 , 39 ]. As the pH increases toward neutrality (pH 7), the surface charge of the nanocomposite beads becomes more negative.…”
Section: Resultsmentioning
confidence: 99%
“…The mechanism underlying these observations can be attributed to the interplay between pH and the surface charge of the adsorbents. At a lower pH (pH 3), the surface of the nanocomposite beads may carry a net positive charge, which is less favorable for the adsorption of paracetamol, given its predominantly negative charge [ 38 , 39 ]. As the pH increases toward neutrality (pH 7), the surface charge of the nanocomposite beads becomes more negative.…”
Section: Resultsmentioning
confidence: 99%
“…At the same time, Pb 4f 5/2 and 4f 7/2 have two obvious peaks at 143.63 and 138.67 eV, respectively, with an energy gap of 4.96 eV, which is due to the formation of the Pb-O bond. The FTIR spectra at 3351 cm −1 and 1704 cm −1 were found to be related to the coordination of -OH and C-O (carboxyl and carbonyl) groups on OBC, respectively; 1246 cm −1 was the combination of in-plane bending vibration and Pb(II) [52,53]. The peak at 688 cm −1 is Pb-O.…”
Section: Adsorption Mechanismsmentioning
confidence: 95%
“…The determination of the surface charge of the adsorbent based on pH values was carried out by studying the pH zpc (point of zero charge) value across the pH range from 3.0 to 8.0, following the method described in ref. 46. For this, 10 mL of a 0.01 M NaCl solution was adjusted to the desired pH value (pH i ) using 0.1 M HCl(aq) or NaOH(aq).…”
Section: Analysis Of the Structure And Composition Of Composite Membr...mentioning
confidence: 99%