Adsorption–Desorption Process to Separate Dyes from Tanning Wastewaters

Abstract

Wastewater production is a major environmental issue for the leather and textile industries: in a modern plant, several synthetic dyes are used in separated coloring batches whose wastewaters are usually mixed, diluted with other process water streams, and sent to a unique wastewater treatment plant. This includes specific physical and biochemical tertiary treatments to remove dyes efficiently. One of the main difficulties of these processes is the presence of multiple dyes, which cannot be treated with the same efficiency as a “wide-spectrum” process. This work explores the possibility of using conventional granular activated carbon (GAC) and a new polyurethane foam (PUF) for the adsorption of an acid red dye in the wastewater of a specific coloring batch of the tanning industry. The aim of this work is twofold: on the one hand, we aim to explore the performance of the new PUF sorbent; on the other hand, we aim to explore the possibility of using adsorption as an optimized pre-treatment for single-dye batches, which may take advantage of the presence of a single type of target dye and its higher concentration. The effluent is then sent to the wastewater treatment plant for further depuration.