Adsorption and surface oxidation of Fe(II) on metal (hydr)oxides

Hiemstra, Tjisse; Riemsdijk, W.H. van

doi:10.1016/j.gca.2007.09.030

Cited by 143 publications

(125 citation statements)

References 108 publications

Supporting

Mentioning

109

Contrasting

Unclassified

Order By: Relevance

“…A strong correlation existed between the As and Fe concentrations ( Figure 1A), indicating that most of the As was associated with Fe particles and aggregates. The specific surface of the nanoparticle aggregates was expected to be higher than the well crystallized Fe(III)-oxyhydroxides (Hiemstra and van Riemsdijk, 2007). Arsenic was therefore more likely to be bound as a bidentate complex to Fe nanoparticles aggregates (Ona-Nguema et al, 2009).…”

Section: As Speciation As a Function Of The Size Fractionmentioning

confidence: 99%

Highlighting the wide variability in arsenic speciation in wetlands: A new insight into the control of the behavior of arsenic

Guénet

Davranche

Vantelon

et al. 2017

Geochimica et Cosmochimica Acta

View full text Add to dashboard Cite

Highlighting the wide variability in arsenic speciation in wetlands: a new insight into the control of the behavior of arsenic. Geochimica et Cosmochimica Acta, Elsevier, 2017, 203, pp.284-302 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. 1Highlighting the wide variability in arsenic speciation in wetlands: AbstractAlthough the behavior of Arsenic (As) under reducing conditions in periods of high water levels in wetlands is well understood and documented, there is a lack of information under oxidizing conditions when the water level decreases. In this study, we were interested in the first stage of the oxidizing period, when oxidation products are still in suspension. A soil sample from the Naizin Kervidy wetland (France) was incubated in the laboratory to produce a reduced soil solution. The reduced solution was subsequently oxidized, filtered and ultrafiltered using decreasing pore size membranes (5 µm, 3 µm, 0.2 µm, 30 kDa and 5 kDa). The distribution of As and Fe was investigated in each size fraction of the oxidized solution and their speciations were studied using XAS, HPLC and SEC-ICP-MS. Organic matter was characterized using thermally assisted hydrolysis and methylation gas chromatography-mass spectrometry (THM-GC-MS) and fluorescence spectroscopy. The majority of the As was present as As(V) but a small amount of As(III) still remained despite the advanced oxidized conditions. In the > 0.2 µm fractions, the XAS analyses showed that As was associated, in the second shell, with Fe (As-Fe = 3.35 Å) as bidentate binuclear complexes and C (As-C = 2.90 Å), suggesting the integration of As in biological objects. In the < 30 kDa fraction, As was directly bound to C (As-C = 1.96 Å) in the first shell indicating the presence of organic As species. In the second shell, an As-Fe distance of 3.35 Å was found showing that 2 part of the As was still complexed with Fe. The 0.2 µm-30 kDa fraction was a transitional fraction in terms of the Fe species and OM composition. In this fraction, organic matter exhibited a more humic character (aromatic molecules) inducing an increasing cation binding capacity. As a consequence, in this fraction and in the smallest one, As, Fe and OM seemed to form ternary complexes in which the Fe or nano-oxides in the > 30 kDa fraction and as monomer, or cluster in < 30 kDa fraction acted as a bridge. In all of the fractions, a proportion of As(V) was present as organic methylated species. These organic species might be produced by several organisms (animal or plant) via a detoxification process. They seemed to be bound to the particulate and colloidal Fe/OM phases as well as integ...

show abstract

Section: As Speciation As a Function Of The Size Fractionmentioning

confidence: 99%

Highlighting the wide variability in arsenic speciation in wetlands: A new insight into the control of the behavior of arsenic

Guénet

Davranche

Vantelon

et al. 2017

Geochimica et Cosmochimica Acta

View full text Add to dashboard Cite

show abstract

“…Half reaction (Equation (38)) can result in a film of NaOH coating [201] the ZVI and a corrosion scale (Fe(OH)2, GR1, FeOOH) coating the ZVI [18, [68][69][70][71][72][73][74][75][76][77]87,88,93,94,96,[110][111][112]167,172,173,176,191,[202][203][204]. This model [150] results (as demonstrated in Section 4) in the amount of NaCl removed (and corrosion scale formed on the ZVI particles) being directly proportional to the inherent charge generated by ZVM TP/ZVM TPA, via the Nernst relationships [150], where [150]:…”

Section: Economic Implications Of Corrosion Scalementioning

confidence: 99%

Desalination of Water Using ZVI (Fe0)

Antia¹

2015

Water

196

View full text Add to dashboard Cite

Batch treatment of water (0.2 to 240 L) using Fe 0 (44,000-77,000 nm) in a diffusion environment operated (at −8 to 25 °C) using: (a) no external energy; (b) pressurized (<0.1 MPa) air; (c) pressurized (<0.1 MPa) acidic gas (CO2); (d) pressurized (<0.1 MPa) anoxic gas (N2); (e) pressurized (<0.1 MPa) anoxic, acidic, reducing gas (H2 + CO + CO2 + CH4 + N2), reduces the salinity of water. Desalination costs increase with increasing NaCl removal. The cost of reducing water salinity from: (i) 2.65 to 1.55 g·L . Desalination is accompanied by the removal, from the water, of one or more of: nitrate, chloride, fluoride, sulphate, phosphate, As, B, Ba, Ca, Cd, Co, Cu, Fe, Mg, Mn, Na, Ni, P, S, Si, Sr, Zn. The rate of desalination is enhanced by increasing temperatures and increasing HCO3 − /CO3 2− concentrations. The rate of desalination decreases with increasing SO4 2− removal under acidic, or pH neutral, operating conditions.

show abstract

“…After directly pumping, the raw groundwater was relatively anoxic with DO about 2.11 mg/L, and had low ORP (8.8 mV). In this reducing condition, the concentration of iron and manganese were slightly over the current Chinese standards for drinking water (GB 5749-2006) and existing mainly as dissoluble Fe(II) and Mn(II) (Hiemstra and Van Riemsdijk, 2007). Total arsenic (As(tot)) concentration of 44.7 μg/L was greatly higher than the maximum contaminant level of Chinese Drinking Water Standard (10 μg/L).…”

Section: Groundwater Characterization and The Adjustment Of Operationmentioning

confidence: 76%

Practical performance and its efficiency of arsenic removal from groundwater using Fe-Mn binary oxide

Chang

Liu

et al. 2010

Journal of Environmental Sciences

View full text Add to dashboard Cite

A treatment unit packed by granular adsorbent of Fe-Mn binary oxide incorporated into diatomite (FMBO(1:1)-diatomite) was studied to remove arsenic from anaerobic groundwater without any pre-treatment or post-treatment. The raw anaerobic groundwater containing 35-45 μg/L of arsenic was collected from suburb of Beijing. Arsenic(III) constituted roughly 60%-80% of the total arsenic content. Approximately 7,000 bed volumes (ratio of effluent volume to adsorbent volume) treated water with arsenic concentration below 10 μg/L were produced in the operation period of four months. The regeneration of FMBO(1:1)-diatomite had been operated for 15 times. In the first stage, the regeneration process significantly improved the adsorption capacity of FMBO(1:1)-diatomite. With increased loading amount of Fe-Mn binary oxide, the adsorption capacity for arsenic decreased 20%-40%. Iron and manganese in anaerobic groundwater were oxidized and adsorptive filtrated by FMBO(1:1)-diatomite efficiently. The final concentrations of iron and manganese in effluents were nearly zero. The continued safe performance of the treatment units proved that adsorbent FMBO(1:1)-diatomite had high oxidation ability and exhibited strong adsorptive filtration.

show abstract

Adsorption and surface oxidation of Fe(II) on metal (hydr)oxides

Cited by 143 publications

References 108 publications

Highlighting the wide variability in arsenic speciation in wetlands: A new insight into the control of the behavior of arsenic

Highlighting the wide variability in arsenic speciation in wetlands: A new insight into the control of the behavior of arsenic

Desalination of Water Using ZVI (Fe0)

Practical performance and its efficiency of arsenic removal from groundwater using Fe-Mn binary oxide

Contact Info

Product

Resources

About