Adsorption and separation of xylene isomers vapors onto the chromium terephthalate-based porous material MIL-101(Cr): An experimental and computational study

Adsorption of volatile organic compounds by ZIF-8, Cu-BTC and a Prussian blue analogue: A comparative study

“…[13][14][15] Among these, two families of molecule-based materials have been extensively investigated in the scope the gas separation: Metal-Organic Frameworks (MOFs) and porous cyano-bridged coordination polymers called Prussian Blue Analogous (PBA). [14,[16][17][18] MOFs materials have been widely investigated for adsorption of different gas and species, [19][20][21][22] but only a few works may be cited on the investigation of their hydrophilic/ hydrophobic behavior and hydrostability. [17] Moreover, there are no detailed studies on their materials efficiency and precise description of the separation/adsorption processes in the presence of water and particularly on the competitive adsorption.…”

Highly Selective, High‐Capacity Separation of o‐Xylene from C8 Aromatics by a Switching Adsorbent Layered Material

“…At 298 K, P s occurred at P/P 0 % 25 %, 30 %, 50 %, and 70 %for OX,PX, MX, and EB, respectively.Uptakes of OX and PX were exceptionally high (8.0 mmol g À1 or 85 wt %) at P/P o % 95 %, second only to MIL-101(Cr). [14] MX and EB did not reach full loading, an indication that higher MX and EB vapor pressure or longer equilibrium time was necessary (Supporting Information, Figure S7). Theadsorbed C 8 molecules are removed in vacuo to recycle the sorbent, as revealed by PXRD (Supporting Information, Figure S2) and recyclability tests (Supporting Information, Figures S9 and S10).…”

Metal organic frameworks as sorption media for volatile and semi-volatile organic compounds at ambient conditions

“…To date, numerous reports have been made to describe the adsorption capacity (and characteristics) of MOFs against common VOCs like aromatic hydrocarbons (e.g., benzene, toluene, and xylene) 14 20 21 22 23 24 . There is yet a paucity of quantitative data on their capacity toward semi-volatile organic species such as C 2 –C 5 VFAs, phenolic, and indolic compounds.…”