Adsorbed Leucaena protein on citrate modified Fe3O4 nanoparticles: synthesis, characterization, and its application as magnetic coagulant

Abstract

Natural coagulants from plants resources have gained a lot of attention as it is renewable, biodegradable, non-hazardous, lower cost, and less sludge generated compared to chemical coagulants. However there are still some drawbacks, namely long settling time and possible increase of dissolved organic carbon in the treated water. In this paper we tried to address these drawbacks by utilizing citrate modified Fe3O4 to adsorb protein from Leucaena leucocephala as the active coagulating agent. The effect of trisodium citrate concentration and protein adsorption pH to the adsorbed protein was investigated. It was found that the trisodium citrate concentration of 0.5 M and pH 4.0 gave the highest protein adsorption. The obtained magnetic coagulant was furthermore characterized using SEM, XRD, FTIR, and TEM, to observe the characteristics before and after protein adsorption. Furthermore the effect of pH (2.0 to 10.0) and coagulant dosage (60 to 600 mg L-1) to the removal of synthetic Congo red wastewater and sludge volume formation was investigated. It was found that pH 3.0 was the best pH for coagulation due to charge neutralization mechanism of leucaena protein. Furthermore the highest removal was obtained at dosage 420 mg L-1 with 80% removal. This result was comparable with crude extract of leucaena with half settling time (20 min) and lower increase of permanganate value, indicating lower increase of dissolved organics in the treated water.

Synthesis of Magnetic Chitosan Composite Beads as an Adsorbent for Removal of Organic Matter from Peat Water

“…The procedure for determining the optimum pH for reducing organic matter from peat water refers to the research of Kristianto et al [14] with some modifications. Each KMB and KMBG (100 mg) was added into each bottle containing 100 mL of peat water, where the pH of the peat water was varied to 2, 3, 4, and 5 by adding 0.1 M hydrochloric acid solution, then stirred using a shaker at 210 rpm for 30 minutes.…”

“…The procedure for determining the optimum mass for removing organic matter from peat water refers to the research of Kristianto et al [14] with several modifications. Each KMB and KMBG was added into 100 mL of peat water at optimum pH with the different masses of the beads of 50, 70, 100, 200, and 300 mg, then stirred using a shaker at 210 rpm for 30 minutes.…”