Entanglement between two electrons belonging to an auto-ionization system and a neighbor twolevel atom produced by the dipole-dipole interaction is studied. The entanglement is quantified using the quadratic negativity of a bipartite system including the continuum of states. Suitable conditions for the generation of highly entangled states of two electrons are revealed. Internal structure of the entanglement is elucidated using the spectral density of quadratic negativity.