Adhesion Between Rubber Compound and Copper-Film-Plated Steel Cord

Cho, Pyong Lae; Jeon, Gyung Soo; Ryu, Seung Kyun; Seo, Gon

doi:10.1080/00218469908009558

Cited by 19 publications

(4 citation statements)

References 13 publications

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“…The non-uniformity of the coatings could be attributed to the initial surface roughness, very less time allowed for coating deposition and the self-limiting nature of the immersion coating technique. Presence of uncoated spots at surface after immersion coating was also reported by Stout et al and Cho et al [1,12,13]. As Fe does not react with sulfur, the bare spots at surface do not adhere to rubber due to lack of chemical bond formation.…”

Section: Coating Composition and Surface Coverage With Sn Concentrati...supporting

confidence: 75%

“…The interfacial bond formation after rubber vulcanization on the coatings was investigated through AES and XPS. Cho et al deposited thin film (30 -90 nm) of copper on uniform surface of zinc-plated steel wires by displacement coating and reported high adhesion ascribed to the optimum formation of copper sulfide at the interface [12,13]. However, very limited study on the effect of Sn content on the interfacial adhesion has been reported so far in the literature.…”

Section: Introductionmentioning

confidence: 99%

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Role of Sn on the Adhesion between Cu-Sn Alloy Coated Steel and SBR Based Rubber

Banerjee

Dutta

Bhowmick

et al. 2014

MSF

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The effect of Cu-Sn coating on steel towards improving the adhesion between steel and typical styrene butadiene rubber (SBR) based tyre bead composition has been investigated in this work. Steel coupons were coated with varying compositions of Cu-Sn via immersion coating, where the electrolyte bath composition was varied. Chemical analysis of the coatings using ICP-OES confirmed increase in Sn content with increasing SnSO4 concentration in the coating baths, keeping other parameters constant. No change in the coating weight was observed with change in Sn concentration in the coatings. Bare spots on the coating surface was observed under SEM XPS analysis confirmed formation of Fe oxide at the bare locations. The coated steel plates were vulcanized with SBR based rubber and peel strength was measured. The results confirmed an optimum Sn concentration of 3 - 4 wt% in the coatings up to which an increase (~ 25%) in adhesion strength was exhibited compared to only Cu coatings. Stereo-microscopic analysis of the peel tested samples validated mixed mode i.e. both adhesive and cohesive modes of failure.

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Section: Coating Composition and Surface Coverage With Sn Concentrati...supporting

confidence: 75%

Section: Introductionmentioning

confidence: 99%

Role of Sn on the Adhesion between Cu-Sn Alloy Coated Steel and SBR Based Rubber

Banerjee

Dutta

Bhowmick

et al. 2014

MSF

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show abstract

“…Also, the non-uniformity of the coatings could be attributed to the self-limiting nature of the immersion coating technique. Presence of uncoated spots at surface after immersion coating was also reported by Stout et al and Cho et al 1,17,18) As Fe does not react with sulfur, the bare spots at surface do not adhere to rubber due to lack of chemical bond formation. The problem of bare spots in case of immersion coating of highly rough surface was addressed by forming multilayer coatings.…”

Section: Effect Of Sn Concentration Increase In Bath On the Surface Rmentioning

confidence: 56%

“…The problem of bare spots in case of immersion coating of highly rough surface was addressed by forming multilayer coatings. 17,18) This issue has been discussed in detail in section 3.3 while discussing the peel test results.…”

Section: Effect Of Sn Concentration Increase In Bath On the Surface Rmentioning

confidence: 99%

Effect of Sn on the Adhesion between Cu–Sn Alloy Coated Steel and Styrene Butadiene Based Rubber

Banerjee¹,

Dutta²,

Bhowmick³

et al. 2014

ISIJ Int.

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The effect of Cu-Sn coating on steel towards improving the adhesion between steel and typical styrene butadiene rubber (SBR) based tyre bead composition has been investigated in this work. Steel coupons were coated with varying compositions of Cu-Sn via immersion coating, where the electrolyte bath composition was varied. Chemical analysis of the coatings using ICP-OES confirmed increase in Sn content with increasing SnSO4 concentration in the coating baths, keeping other parameters constant. No change in the surface roughness and coating weight was observed with change in Sn concentration in the coatings. The coated steel plates were vulcanized with SBR based rubber and peel strength was measured. The results confirmed an optimum Sn concentration of 3-4 wt% in the coatings up to which an increase (~ 25%) in adhesion strength was exhibited compared to only Cu coatings. Stereo-microscopic analysis of the peel tested samples validated mixed mode i.e. both adhesive and cohesive modes of failure.

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Effects of cure levels on adhesion between rubber and brass in the composites made up of rubber compound and brass-plated steel cord

Jeon¹,

Seo

2003

Korean J. Chem. Eng.

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Adhesion Between Rubber Compound and Copper-Film-Plated Steel Cord

Cited by 19 publications

References 13 publications

Role of Sn on the Adhesion between Cu-Sn Alloy Coated Steel and SBR Based Rubber

Role of Sn on the Adhesion between Cu-Sn Alloy Coated Steel and SBR Based Rubber

Effect of Sn on the Adhesion between Cu–Sn Alloy Coated Steel and Styrene Butadiene Based Rubber

Effects of cure levels on adhesion between rubber and brass in the composites made up of rubber compound and brass-plated steel cord

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