Adeninium 3-carboxyanilinium bis(perchlorate) trihydrate

Abstract

In the title salt, C5H6N5 +·C7H8NO2 +·2ClO4 −·3H2O, the 3-carboxy­anilinium and adeninium cations are monoprotonated at the amino group and at a pyrimidine N atom respectively. In the crystal, the components are involved in extensive three-dimensional hydrogen-bonding networks composed of O—H⋯O, N—H⋯O, O—H⋯N, N—H⋯N and C—H⋯O inter­actions. Bifurcated hydrogen bonds are observed between perchlorate O atoms and adeninium cations.

Antispasmodic activity of novel 2,4-dichloroanilinium perchlorate hybrid material (I): X-ray crystallography, DFT studies, and molecular docking approach

“…In fact, the widespread occurrence of perchlorates has generated considerable interest in diverse elds, particularly, stabilization of PVC, catalysis and pharmacology [11][12][13]. As a result, perchlorates have been often employed as inorganic building blocks in hybrid compounds with multi-dimensional shapes likely chains, ribbons, layers, or three-dimensional arrangements [14][15][16]. Bene ting from structural diversities and characteristics of hybrid materials, organic components are an appealing part of hybrid materials, which play important roles in affecting their physical properties.…”

The C6H4(NH3)2(NO3)2 assembly investigations: Crystal structure, optical properties and impedance spectroscopy, electrical relaxation with Ac conductivity studies

“…Several organic cations (protonated amines) can be used to stabilize these anions, especially acidic anions [14 -16]. The organic molecule, such as length, geometry and relative position of the donor groups, play a very important role in interesting three-dimensional networks, layers, chains and ribbon structures [17][18][19].…”