Additions and Corrections-Amino Derivatives of 2,2'Diphenylcyclohexanone

Burger, Alfred; Bennet, William B.

doi:10.1021/ja01156a622

J. Am. Chem. Soc.

1951

DOI: 10.1021/ja01156a622

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Additions and Corrections-Amino Derivatives of 2,2'Diphenylcyclohexanone

Alfred Burger¹,

William B. Bennet²

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1983

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“…kinetics of two medium gravity oils (19.9" and 27.I"API). His experiments, which were conducted in a packed, tubular reactor, gave reaction orders with respect to oxygen, in the range 0.5 to 1 .O which compare favourably with values reported by others (Warren, Reed and Price, 1960, Burger, 1976, Tadema and Weijdema, 1970, Smith and Perkins, 1973.…”

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Low temperature oxidation of athabasca bitumen

Babu

Cormack

1983

Can J Chem Eng

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The kinetics of low temperature oxidation in the Athabasca oil sands were investigated over the temperature range 373 K to 459 K. Oxidation experiments, in which the sand‐free bitumen was vigorously stirred to obtain a homogeneous oxygen concentration throughout the bitumen, were carried out. It was concluded that the oxidation reaction is governed by three different kinetic expressions depending on temperature and past oxidation history. These are: (i) a high rate first order regime which is obeyed at low extents of oxidation and at temperatures below approximately 423 K; (ii) a second order regime, obeyed at low extents of oxidation and at temperatures greater than 423 K; and (iii) a low rate first order regime, obeyed for extents of oxidation greater than 1.7 moles O2/kg bitumen over the entire temperature range investigated. The partial molar enthalpy of low temperature oxidation was also evaluated, and was found to be constant over the range of oxidation extents studied.

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confidence: 86%

Low temperature oxidation of athabasca bitumen

Babu

Cormack

1983

Can J Chem Eng

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Additions and Corrections-Amino Derivatives of 2,2'Diphenylcyclohexanone

Cited by 1 publication

References 0 publications

Low temperature oxidation of athabasca bitumen

Low temperature oxidation of athabasca bitumen

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