The reactions of [Re(CO)6]+, [FeCp(CO)2CS]+ and [FeCp(CNPh)3]+ with the metallo nitrile ylides [M–{C+=N–C–(H)CO2Et}(CO)5]– (M = Cr, W) and the chromio nitrile imine [Cr–{C+=N–N–H}(CO)5]– (generated by mono‐α‐deprotonation of the parent isocyanide complexes) to give neutral 5‐metallated 1,3‐oxazolin‐ (1), 1,3‐thiazolin‐ (2), imidazolin‐ (3, 4), 1,3,4‐oxdiazolin‐ (5), 1,3,4‐thiadiazolin‐ (6) and 1,3,4‐triazolin‐2‐ylidene (8) chromium and tungsten complexes represent the first all‐organometallic versions of Huisgen’s 1,3‐dipolar cycloadditions. The formation of 6 and 8 is accompanied by partial decomposition to (OC)5Cr–C≡N–FeCpL2 {L = CO (7), CNPh (9)}. The structures of 4a and 5 have been characterized by X‐ray diffraction.