Light with transverse polarization structure, such as radial and azimuthal polarization, enables and revives lots of applications based on light-matter interaction due to their unique focal properties. To date, studies referring to this topic mainly concentrate in weak-light domain, yet it should have gained more attention in strong-light domain. A main factor contributing to the current situation is that the generation devices cannot afford high power. Here, in this proof-of-principle work, we demonstrate the generation of strong single-longitudinal-mode (SLM) cylindrical vector (CV) short pulses via stimulated Brillouin amplification, specifically, the energy is transferred from a 700 ps pump to a 300 ps Stokes pulse via parametrically generated coherent phonons. After amplification, a 100 mJ-level SLM CV pulse light with 300 ps duration is obtained. Meanwhile, the phase and polarization structures are high fidelity maintained. This result provides a practicable way to generate strong CV light, and by extending this mechanism into multi-pump beam combing system, even an ultra-high intensity CV light can be expected.Science of structured light-the generation and application of light fields with custom transverse intensity, phase and polarization profiles-has gained enormous progress and gradually become the hottest topic of optical community over the past decade. 1,2 In this new subject of modem optics, orbital angular momentum (OAM) 3 plays a crucial role, which is associated with light's twisted phase profile. Particularly, the infinite dimensional space spanned by this degree-of-freedom (DOF) has directly given rise to a promising research direction of the topic-informatics, including both classical and quantum domains. 4 In addition to intensity and phase structures, the polarization of light can also exhibit a non-uniform transverse distribution once the OAM and spin angular momentum (SAM) DOFs are entangled. 5,6 Among them, radially and azimuthally polarized light, two specific members of the so-called cylindrical vector (CV) beam, have received more attention, because their focal a) Zhi-Han Zhu and Peng Chen contributed equally to this work. b) Electronic