Activation of hydrogen and methane by thermalized FeO+ in the gas phase as studied by multiple mass spectrometric techniques

Vibrational spectroscopy of intermediates in benzene-to-pheno conversion by FeO+

“…As a result, FeO ϩ reacts with benzene at the collision rate [9], while it reacts with methane at only ϳ20% of the collision rate [30,31] [9]. This is another significant difference with the FeO ϩ ϩ CH 4 system, where FeOH ϩ ϩ CH 3 is energetically allowed, is a significant product at thermal energies, and dominates at high collision energy [31]. Manganese is the only first-row transition-metal for which MOH ϩ is observed as a product of the MO ϩ ϩ benzene reaction [8].…”

How a Quantum Chemical Topology Analysis Enables Prediction of Electron Density Transfers in Chemical Reactions. The Degenerated Cope Rearrangement of Semibullvalene

“…22,23 TiO 2 , ZrO 2 , and HfO 2 oxides have also been utilized to catalyze the aromatization of C 6+ alkanes. 20 While chemical reactions of the bare transition metal oxide cations with H 2 have received a significant interest, [24][25][26][27][28][29][30][31][32][33][34][35][36][37] neutral metal oxides have gained much less attention. [38][39][40][41][42][43][44][45][46][47][48][49][50] Recently Zhou et al 51 have reported a combined experimental and theoretical study on the hydrogenation reactions by group V metal dioxides using matrix isolation spectroscopy.…”

Coordination chemistry of Fe+, (c-C5H5)Fe+, and (c-C5H5)2Fe+ in the gas phase at room temperature: kinetics of sequential ligation with hydrogen cyanide and cyanoacetylene

“…We have previously surveyed intrinsic features of the kinetics of ion ligation for FeO ϩ [1][2][3] tion with the gas-phase ionic synthesis of metal cyanides, particularly as it may proceed in interstellar environments. For example, for M ϭ Mg, the following two-step interstellar synthesis has been proposed for MgCN [9]:…”