Abstract:The transformation of ethanol to value-added chemicals has tremendous potential. However, generally, harsh reaction conditions are needed for the functionalization of ethanol due to its high dehydrogenation energy. Herein, a metal-free photo-mediated activation of challenging ethanol and higher aliphatic alcohols for the synthesis of differently functionalized benzimidazoles under mild conditions is disclosed. The interplay of a photocatalyst and a HAT reagent facilitated the activation of aliphatic alcohols. … Show more
“…Based on various control experiments and previous literature reports, 26–35 a possible mechanism was proposed for the synthesis of quinazolinones (Fig. 3).…”
The activation and utilization of challenging aliphatic alcohols like methanol and ethanol is a very appealing approach to synthesize valuable organic molecules. Using methanol and ethanol as a coupling partner...
“…Based on various control experiments and previous literature reports, 26–35 a possible mechanism was proposed for the synthesis of quinazolinones (Fig. 3).…”
The activation and utilization of challenging aliphatic alcohols like methanol and ethanol is a very appealing approach to synthesize valuable organic molecules. Using methanol and ethanol as a coupling partner...
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