2019
DOI: 10.1002/celc.201901066
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Activation of Cellobiose Dehydrogenase Bioelectrocatalysis by Carbon Nanoparticles

Abstract: Protein‐nanoparticle (NP) interactions offer a powerful tool to modulate enzymatic activity and activate biocatalysis. However, strong scattering effects may complicate conventional spectrophotometric studies of NP‐assisted biocatalysis. Here, bioelectrocatalytic oxidation of cellobiose by the Humicola insolens cellobiose dehydrogenase (CDH) was electrochemically interrogated with two redox mediators, ferricyanide and cytochrome c, and two types of carbon NPs (CNPs), unmodified (CNP) and negatively charged 4‐s… Show more

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