2023
DOI: 10.26434/chemrxiv-2023-qzkc2
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“Activated Borane” – A Porous Borane Cluster Polymer as an Efficient Lewis Acid-based Catalyst

Abstract: Borane cluster based porous covalent networks, named activated borane (ActB), were prepared by co-thermolysis of decaborane(14) (nido-B10H14) and selected hydrocarbons (toluene – ActB-Tol, cyclohexane – ActB-cyHx, and n-hexane – ActB-nHx) under anaerobic conditions. These amorphous solid powders exhibit different textural and Lewis acid (LA) properties that vary depending on the nature of the constituent organic linker. For ActB-Tol, its LA strength even approaches that of the commonly-used molecular LA, B(C6F… Show more

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