Acridine based metal–organic framework host–guest featuring efficient photoelectrochemical-type photodetector and white LED

Abstract

A novel metal-organic framework (MOF) host-guest material [Cd3(EtOIPA)4(HAD)2]•H2O has been successfully synthesized by the reaction of 5-ethoxyisophthalic acid (EtOIPA), acridine (AD) and Cd(II) salts under hydrothermal conditions. Structurally, the title...

Thickness-dependent characteristics and oxidation of 2D-cadmium

“…24 Furthermore, Wang et al studied the zero-dimensional structures of Cd and predicted that Cd-based clusters generate delocalized pelectron channels, which are used as photoelectrochemical-type photodetectors. 25 Moreover, Ganiga et al reported that quantum dot (QD) CdS is a fluorescence recoverer, therefore it is a promising candidate that can be used in advanced biological sensors. 26 Although various low-dimensional forms of Cd crystals have been studied to date, atomically thin possible two-dimensional crystal structures have not been investigated.…”

Sulfonated covalent organic framework packed Nafion membrane with high proton conductivity for H2/O2fuel cell applications

“…is an effective way to improve the water content and water retention capacity of proton exchange membranes, which is expected to improve the continuity of proton transfer channels and enhance proton transfer. [15][16][17][18][19][20][21] Therefore, it is of great signicance to design and develop new functional packing materials for efficient proton transport.…”

Assembly of an iron-based complex into a metal–organic framework: a space confinement strategy for isolation of mono-iron complexes to protect from dimerization

“…Dispersion of homogenous complexes into the nanochannels of porous materials has drawn considerable attention, especially for researchers specialized in catalysis, [8][9][10] luminescence/sensing, [11][12][13] magnetism, 14,15 and other multifunctional materials. 16 In this context, metal-organic frameworks (MOFs) have emerged as crystalline porous materials consisting of metal-based nodes and multitopic organic linkers connected with coordination bonds.…”