Achiral Solvent Inversed Helical Pathway and Cosolvent Controlled Excited‐State “Majority Rule” in Enantiomeric Dansulfonamide Assemblies
Xin Wen,
Fulin Wang,
Sifan Du
et al.
Abstract:Achiral solvents are commonly utilized to induce the self‐assembly of chiral molecules. This study demonstrates that achiral solvents can trigger helicity inversion in the assemblies of dansyl amphiphiles and control the excited‐state “majority rule” in assemblies composed of pure enantiomers, through variation of the cosolvent ratio. Specifically, enantiomers of dansyl amphiphiles self‐assemble into helical structures with opposite handedness in methanol (MeOH) and acetonitrile (MeCN), together with inversed … Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.