Piezoelectric sensors can be utilized in Lamb-wave-based structural health monitoring (SHM), which is an effective method for aircraft structural damage detection. However, due to the inherent stiffness, brittleness, weight, and thickness of piezoelectric ceramics, their applications in aircraft structures with complex curved surfaces are seriously restricted. Herein, we report a flexible, light-weight, and highperformance BaTiO 3 :Sm 2 O 3 /SrRuO 3 /SrTiO 3 /mica film sensor that can be used in high-temperature SHM of aircraft. Enhanced ferroelectric Curie temperature (487 °C) and piezoelectric coefficient d 33 (120−130 pm/V) are achieved in BaTiO 3 , which can be attributed to the tensile strain developed by stiff Sm 2 O 3 nanopillars. Stable ferroelectricity and piezoelectricity are retained up to 150 °C. The flexible BaTiO 3 :Sm 2 O 3 / SrRuO 3 /SrTiO 3 /mica film is validated as an ultrasonic sensor with high sensitivity and stability for damage monitoring on aircraft structures with the curved surface ranging from 25 to 150 °C. Our work demonstrates that flexible and light-weight BaTiO 3 :Sm 2 O 3 /SrRuO 3 /SrTiO 3 /mica film sensors can be employed as high-temperature piezoelectric sensors for real-time SHM of aircraft structures with complex curved surfaces.