Achieving a high long-term stability for room temperature CO-sensitive Pt-SnO2 composite nanoceramics through two strategies

Wu, Menghan; Gui, Fubing; Lu, Xilai; Yan, Zhiqiao; Chen, Feng; Jin, Ying; Luo, Xiong; Chen, Wanping

doi:10.1016/j.mseb.2022.116070

Cited by 5 publications

(1 citation statement)

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“…Thus, these large grains must have come from their starting materials. According to two very recent papers, large Pt grains are important for room-temperature CO-sensitive and H 2 -sensitive Pt–SnO 2 composite nanoceramics to achieve a high, long-term stability [ 37 , 38 ]. As a matter of fact, these two commercial Au and Pt powders, with relatively large particles, had been intentionally chosen as starting materials in this study.…”

Section: Resultsmentioning

confidence: 99%

NO2 Sensing Capability of Pt–Au–SnO2 Composite Nanoceramics at Room Temperature

Song

et al. 2023

Molecules

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Composite ceramics of metal oxides and noble metals have received much attention for sensing reducing gases at room temperature. Presently, composite ceramics of SnO2 and noble metals have been prepared and investigated for sensing oxidizing NO2 at room temperature. While dramatic increases in resistance were observed for both 1 wt% Pt–SnO2 and 5 wt% Au–SnO2 composite nanoceramics after being exposed to NO2 at room temperature, the largest increase in resistance was observed for 1 wt% Pt–5 wt% –Au–SnO2 composite nanoceramics among the three composites. The response to 0.5 ppm NO2-–20% O2–N2 was as high as 875 at room temperature, with a response time of 2566 s and a recovery time of 450 s in the air of 50% relative humidity (RH). Further investigation revealed that water molecules in the air are essential for recovering the resistance of Pt–Au–SnO2 composite nanoceramics. A room temperature NO2-sensing mechanism has been established, in which NO2 molecules are catalyzed by Pt–Au to be chemisorbed on SnO2 at room temperature, and desorbed from SnO2 by the attraction of water molecules in the air. These results suggest that composite ceramics of metal oxides and noble metals should be promising for room temperature sensing, not only reducing gases, but also oxidizing gases.

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Section: Resultsmentioning

confidence: 99%