Accessing Functionalized Furans from Reacting Enynones and Enynals through Furyl Metal Carbenes
Ho‐Jun Cho,
Ju Hyun Kim
Abstract:Enynones and enynals represent donor‐type carbene precursors that efficiently form furyl metal carbenes via a catalytic intramolecular 5‐exo‐dig cyclization and rearrangement cascade, in a 100% atom‐economical manner, using various metals. These furyl metal carbenes have been successfully utilized in numerous carbene reactions, including metal carbene X–H insertion, cyclopropanations, metathesis, and cross‐coupling, demonstrating a broad reaction scope and efficiency in constructing highly functionalized furan… Show more
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