Abstract:Aliphatic trifluoromethyl ketones are a type of unique fluorine‐containing subunit which plays a significant role in altering the physical and biological properties of molecules. However, catalytic methods to provide direct access to aliphatic trifluoromethyl ketones is highly desirable yet remains underdeveloped, partially due to the high reactivity and instability of trifluoroacetyl radical. Herein, we report a photocatalytic synthesis of trifluoromethyl ketones from alkyl bromides with trifluoroacetic anhyd… Show more
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