1964
DOI: 10.1021/ac60210a064
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Absorptivities for Infrared Determination of Peroxyacyl Nitrates.

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Cited by 64 publications
(31 citation statements)
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“…All the reactions reported were carried out in the 610 ft 3 Battelle smog chamber which has been described elsewhere. 14 For all experiments the chamber was maintained at 90° ± 3°F at a relative humidity of 50 ± 5%.…”
Section: Methodsmentioning
confidence: 99%
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“…All the reactions reported were carried out in the 610 ft 3 Battelle smog chamber which has been described elsewhere. 14 For all experiments the chamber was maintained at 90° ± 3°F at a relative humidity of 50 ± 5%.…”
Section: Methodsmentioning
confidence: 99%
“…It appears that reaction (4) plays a part in H0N0 2 formation early in the experiment when the hydroxyl concentration is at its highest, however most of the nitric acid is formed after NO 2 has reached its peak and O3 has begun to accumulate. Hence reactions (1)(2)(3) are the predominant source of H0N0 2 . This observation is also supported by the fact that almost all investigators report a good nitrogen balance up to the time when NO 2 maximizes.…”
Section: Kinetics and Mechanismmentioning
confidence: 99%
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“…Each source tank of PAN was analyzed by infrared absorption (Perkin-Elmer, 683) prior to each experimental exposure. 4 Aliquots from a single tank were diluted in a known volume to obtain known concentrations for the calibration of the gas chromatograph. The resulting calibration curve was used in obtaining the concentration in the chamber.…”
Section: Methodsmentioning
confidence: 99%
“…The concentration may be determined by measurement with flame ionization chromatography or by infrared absorption spectrophotometry. 8 The spectrum can also be examined for the presence of impurities. An eight-hour reactor run yields enough PAN to make 1500 ppm at 100 psig in an LPO tank.…”
Section: Storage and Handlingmentioning
confidence: 99%